Аннотация:
A cyclic voltammetry study of the η5-pentamethylcyclopentadienylrhodium (Cp*Rh) complexes [(Cp*Rh)2(μ.-Cl)3]+ and [Cp*RhIIIaq]2+ at pH 6.05 in the absence and in the presence of nicotinamide cofactors indicates that the chloro complex is more advantageous for electrochemical reduction of NAD+ into NADH; the reverse oxidation of NADH by [(Cp*Rh)2(μ-CI)3]+ is insufficiently selective for practical applications according to the 1H NMR data.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
U. Koelle, A. D. Ryabov, “The Effect of Chloride on the Electroreduction of NAD+ in the Presence of [Cp*RhIII]2+ Species”, Mendeleev Commun., 5:5 (1995), 187–189
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc5091
https://www.mathnet.ru/rus/mendc/v5/i5/p187
Эта публикация цитируется в следующих 8 статьяx:
Wassim El Housseini, François Lapicque, Alain Walcarius, Mathieu Etienne, “A hybrid electrochemical flow reactor to couple H2 oxidation to NADH regeneration for biochemical reactions”, Electrochemical Science Adv, 2:4 (2022)
Alain Walcarius, Rihab Nasraoui, Zhijie Wang, Fengli Qu, Veronika Urbanova, Mathieu Etienne, Mehmet Göllü, Ayhan S. Demir, Janine Gajdzik, Rolf Hempelmann, “Factors affecting the electrochemical regeneration of NADH by (2,2′-bipyridyl) (pentamethylcyclopentadienyl)-rhodium complexes: Impact on their immobilization onto electrode surfaces”, Bioelectrochemistry, 82:1 (2011), 46
Zoran Mandić, Blaženka Gašparović, Zlatko Weitner, “Electrochemical reduction of at Hg/phosphate electrolyte interface”, Journal of Electroanalytical Chemistry, 587:2 (2006), 314
A. Deronzier, J.-C. Moutet, Comprehensive Coordination Chemistry II, 2003, 471
Eugenii Katz, Andrew N. Shipway, Itamar Willner, Encyclopedia of Electrochemistry, 2002
Lo Gorton, Elena Domínguez, Encyclopedia of Electrochemistry, 2002
Seiji Ogo, Olivier Buriez, John B Kerr, Richard H Fish, “Bioorganometallic chemistry”, Journal of Organometallic Chemistry, 589:1 (1999), 66
Richard H. Fish, “Bioorganometallic chemistry: synthesis, structure, and molecular recognition chemistry of (η5-pentamethylcyclopentadienyl)rhodium–DNA/RNA complexes in water”, Coordination Chemistry Reviews, 185-186 (1999), 569
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