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Эта публикация цитируется в 7 научных статьях (всего в 7 статьях)
A Highly Efficient, Indirect Electrooxidation of 6β-Methyl-3β,5α-dihydroxy-16α17α-cyclohexanopregnan-20-one to the Corresponding 5α-Hydroxy-3,20-dione Using a Mediatory Couple of Sodium Bromide and Substituted 2,2,6,6-Tetramethylpiperidine-N-oxyl (TEMPO)
Yu. N. Ogibin, I. S. Levina, A. V. Kamernitskii, G. I. Nikishin
N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
Аннотация:
A cyclic voltammetry study of the η5-pentamethylcyclopentadi-enylrhodium (Cp&z.supast;Rh) complexes [(Cp&z.supast;Rh)2(μ-Cl)3]+ and [Cp&z.supast;RhIIIaq]2+ at pH 6.05 in the absence and in the presence of nicotinamide cofactors indicates that the chloro complex is more advantageous for electrochemical reduction of NAD+ into NADH; the reverse oxidation of NADH by [(Cp&z.supast;Rh)2(μ-Cl)3]+ is insufficiently selective for practical applications according to the 1H NMR data.
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https://www.mathnet.ru/rus/mendc5089
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