Аннотация:
Quantum rate constant evaluations and kinetic isotope effects for the oxidative addition of CH4 (and CD4) to a bare Pd atom, calculated in terms of the Reaction Path Hamiltonian approximation, show quantum tunneling to play a very important role in the process when T < 200 K.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
V. M. Mamaev, I. P. Gloriozov, S. Ya. Ishchenko, V. V. Simonyan, E. M. Myshakin, A. V. Prisyajnuk, Yu. A. Ustynyuk, “Tunneling in the Oxidative Addition Reaction of Methane to a Bare Palladium Atom”, Mendeleev Commun., 5:4 (1995), 137–138
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc5068
https://www.mathnet.ru/rus/mendc/v5/i4/p137
Эта публикация цитируется в следующих 1 статьяx:
Catalysis by Metal Complexes, 21, Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes, 2002, 219