Аннотация:
A combination of the Homer–Emmons synthesis of alkyl 2,4-dienoates with their hydrogenation over complex L·Cr(CO)3 catalysts (L = arene or 3CO) provides a versatile, stereocontrolled approach to olefins with a homoallylic pattern of functional substitution, such as certain insect pheromones or (Z)-prenylated arenes analogous to the “left-side” moiety of bifurcarenone.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
A. A. Vasil'ev, G. V. Kryshtal', E. P. Serebryakov, “A Convenient Protocol for the Stereocontrolled Synthesis of Olefins with a Homoallylic Type of Functionality”, Mendeleev Commun., 5:2 (1995), 41–42
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc5022
https://www.mathnet.ru/rus/mendc/v5/i2/p41
Эта публикация цитируется в следующих 11 статьяx:
A. A. Vasil'ev, I. V. Kuchurov, S. G. Zlotin, “1,4-cis-Hydrogenation of butyl sorbate in supercritical carbon dioxide”, Russ Chem Bull, 67:5 (2018), 923
A. A. Vasil'ev, L. Engman, V. M. Merkulova, “Synthesis of 3(Z)-dodecen-12-olide—an aggregation pheromone of the flat grain beetleCryptolestes pusillus (Coleoptera:Cucujidae)”, Russ Chem Bull, 49:7 (2000), 1297
A. A. Vasil'ev, L. Engman, E. P. Serebryakov, “Alkene–alkyne metathesis and 1,4-cis-hydrogenation as a route to tetrasubstituted (Z)-olefins”, Mendeleev Commun., 10:3 (2000), 101–103
Н. Я. Григорьева, П. Г. Циклаури, “Синтезы феромонов насекомых, относящихся к группе (Z)-тризамещенных олефинов”, Усп. хим., 69:7 (2000), 624–641; N. Ya. Grigorieva, P. G. Tsiklauri, “Synthesis of insect pheromones belonging to the group of (Z)-trisubstituted alkenes”, Russian Chem. Reviews, 69:7 (2000), 573–589
E. P. Serebryakov, A. A. Vasil'ev, D. Yu. Titskii, I. P. Beletskaya, “(η6-Naphthalene)tricarbonylchromium-mediated hydrogenation of 3,5-diene-1,7-diynes as a route to (Z,Z,Z)-1,4,7-trienes”, Mendeleev Commun., 10:5 (2000), 168–170
G. V. Kryshtal', G. M. Zhdankina, E. P. Serebryakov, “Regioselectivity in the C-alkylation of triethyl 3-methyl-4-phosphonobut-2-enoate”, Russ Chem Bull, 46:10 (1997), 1745
A. A. Vasil'ev, E. P. Serebryakov, “A simple synthesis of 4E,7Z-tridecadien-1-yl acetate, a component of the sex pheromone of the potato mothPhtorimaea operculella (Lepidoptera:Gelehiidae)”, Russ Chem Bull, 45:9 (1996), 2232
Andrei A. Vasil'ev, Alexei L. Vlasyuk, Galina D. Gamalevich, Edward P. Serebryakov, “A versatile and convenient protocol for the stereocontrolled synthesis of olefinic insect pheromones”, Bioorganic & Medicinal Chemistry, 4:3 (1996), 389
G. V. Kryshtal, E. P. Serebryakov, “Regio- and stereoselectivity in the addition reactions of CH-acids to aldehydes under the conditions of phase-transfer catalysis”, Russ Chem Bull, 44:10 (1995), 1785
A. A. Vasil'ev, A. L. Vlasyuk, G. V. Kryshtal, E. P. Serebryakov, “Stereospecific syntheses of sex pheromones of the californian red scale and white peach scale (Homoptera:Diaspididae) based on 1,4-cis-hydrogenation of dienes”, Russ Chem Bull, 44:10 (1995), 1946
A. A. VASIL'EV, G. V. KRYSHTAL, E. P. SEREBRYAKOV, “ChemInform Abstract: A Convenient Protocol for the Stereocontrolled Synthesis of Olefins with a Homoallylic Type of Functionality.”, ChemInform, 26:33 (1995)