Аннотация:
The selective photolysis of α-azido groups in 2,4,6-triazido-3,5-dichloropyridine has been explained by the orbital control of the azido group photodynamic dissociation processes.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
S. V. Chapyshev, R. Walton, P. M. Lahti, “Orbital control in the selective photolysis of azido groups of 2,4,6-triazido-3,6-dichloropyridine”, Mendeleev Commun., 10:5 (2000), 187–188
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc4449
https://www.mathnet.ru/rus/mendc/v10/i5/p187
Эта публикация цитируется в следующих 23 статьяx:
Sergei V. Chapyshev, Denis V. Korchagin, Paulo Costa, Wolfram Sander, “The powder X‐band electron paramagnetic resonance spectroscopy of septet pyridyl‐2,4,6‐trinitrene”, Magnetic Reson in Chemistry, 60:8 (2022), 829
Sergei V. Chapyshev, Enrique Mendez‐Vega, Wolfram Sander, “Molecular Magnets: The Synthesis and Characterization of High‐Spin Nitrenes”, Chemistry A European J, 27:4 (2021), 1258
С. В. Чапышев, Д. В. Корчагин, Е. Я. Мисочко, “Последние достижения в химии высокоспиновых нитренов”, Усп. хим., 90:1 (2021), 39–69; S. V. Chapyshev, D. V. Korchagin, E. Ya. Misochko, “Recent advances in chemistry of high-spin nitrenes”, Russian Chem. Reviews, 90:1 (2021), 39–69
Silvia E. Loredo-Carrillo, Elisa Leyva, Matthew S. Platz, Agobardo Cárdenas-Chaparro, Antonio Martínez-Richa, “Thermolysis of 2-azido-3-(R-anilino)-1,4-naphthoquinones. Nitrene insertion versus hydrogen abstraction”, Tetrahedron Letters, 61:14 (2020), 151731
Sergei V. Chapyshev, Denis V. Korchagin, Dirk Grote, Wolfram Sander, “EPR spectroscopy of multicomponent, multispin molecular system obtained by the photolysis of 2,4,6‐triazido‐3‐cyano‐5‐fluoropyridine in solid argon”, Magnetic Reson in Chemistry, 57:8 (2019), 472
Sergei Chapyshev, “Six-Membered Aromatic Polyazides: Synthesis and Application”, Molecules, 20:10 (2015), 19142
Sergei V. Chapyshev, Evgeny N. Ushakov, Patrik Neuhaus, Wolfram Sander, “Matrix Isolation, Zero-Field Splitting Parameters, and Photoreactions of Septet 2,4,6-Trinitrenopyrimidines”, J. Org. Chem., 79:13 (2014), 6047
Sergei V Chapyshev, Denis V Korchagin, Patrik Neuhaus, Wolfram Sander, “High-spin intermediates of the photolysis of 2,4,6-triazido-3-chloro-5-fluoropyridine”, Beilstein J. Org. Chem., 9 (2013), 733
Sergei V. Chapyshev, Evgeny N. Ushakov, Alexander V. Chernyak, “15N NMR spectra and reactivity of 2,4,6‐triazidopyridines, 2,4,6‐triazidopyrimidine and 2,4,6‐triazido‐s‐triazine”, Magnetic Reson in Chemistry, 51:9 (2013), 562
Eugenii Ya. Misochko, Alexander V. Akimov, Artem A. Masitov, Denis V. Korchagin, Igor K. Yakushchenko, Sergei V. Chapyshev, “High-spin organic molecules with dominant spin-orbit contribution and unprecedentedly large magnetic anisotropy”, The Journal of Chemical Physics, 137:6 (2012)
Sergei V. Chapyshev, Denis V. Korchagin, Mikhail F. Budyka, Tatiana N. Gavrishova, Patrik Neuhaus, Wolfram Sander, “EPR Studies on Branched High‐Spin Arylnitrenes”, ChemPhysChem, 13:11 (2012), 2721
S. V. Chapyshev, D. V. Korchagin, G. V. Shilov, S. M. Aldoshin, “Synthesis and structure of asymmetric 2,4,6-triazidopyridines”, Chem Heterocycl Comp, 47:7 (2011), 817
D. V. Korchagin, K. V. Bozhenko, S. V. Chapyshev, S. M. Aldoshin, “A quantum-chemical study on the selectivity of photolysis of azido groups in 2,4,6-triazido-3,5-dichloropyridine”, High Energy Chem, 43:4 (2009), 289
E. Ya. Misochko, A. V. Akimov, S. V. Chapyshev, “High resolution electron paramagnetic resonance spectroscopy of septet pyridyl-2,4,6-trinitrene in solid argon: Fine-structure parameters of six electron-spin cluster”, The Journal of Chemical Physics, 129:17 (2008)
Sergei V. Chapyshev, Dirk Grote, Christopher Finke, Wolfram Sander, “Matrix Isolation and EPR Spectroscopy of Septet 3,5-Difluoropyridyl-2,4,6-trinitrene”, J. Org. Chem., 73:18 (2008), 7045
M. F. Budyka, “Photochemistry of aromatic azides and nitrenes”, High Energy Chem, 41:3 (2007), 176
S. I. Kuzina, A. I. Mikhailov, S. V. Chapyshev, “Effect of microwave radiation on the magnetic properties of quintet dinitrenes”, Dokl Phys Chem, 412:2 (2007), 34
S. I. Kuzina, A. I. Mikhailov, S. V. Chapyshev, “Radiolysis and photolysis of crystalline 2,4,6-triazido-3,5-dichloropyridine: Generation of Quintet dinitrenes”, High Energy Chem, 41:4 (2007), 245
S. V. Chapyshev, S. I. Kuzina, A. I. Mikhailov, “Generation of quintet dinitrenes by the γ-radiolysis of crystalline 2,4,6-triazido-3,5-dicyanopyridine”, Mendeleev Commun., 17:4 (2007), 207–208
Sergei V. Chapyshev, Richard Walton, Paul R. Serwinski, Paul M. Lahti, “Quintet State Electron Spin Resonance Spectra of Pyridyldinitrenes”, J. Phys. Chem. A, 108:32 (2004), 6643
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