Аннотация:
Reactions of hexafluorobenzene, pentafluorobenzene, octafluoronaphthalene and pentafluoropyridine with the NiCl2–2,2’-bipyridine (or 1,10-phenanthroline)–Zn reductive catalytic system in DMF (or DMA) in the presence of water or ammonium chloride resulted in the products of C–F bond hydrogenolysis.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
V. F. Starichenko, N. Yu. Adonin, “Hydrogenolysis of C–F bonds in fluorinated aromatic hydrocarbons catalysed by nickel complexes”, Mendeleev Commun., 10:2 (2000), 60–61
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc4381
https://www.mathnet.ru/rus/mendc/v10/i2/p60
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S.A. Prikhod'ko, A Yu. Shabalin, N Yu Adonin, “New catalytic systems with chemically fixed nickel complexes in the reactions of reductive activation of C-F bonds in ionic liquid media”, Journal of Organometallic Chemistry, 950 (2021), 121995
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Shang‐Dong Yang, Homogeneous Catalysis for Unreactive Bond Activation, 2014, 203
Moritz F. Kuehnel, Dieter Lentz, Thomas Braun, “Synthesis of Fluorinated Building Blocks by Transition‐Metal‐Mediated Hydrodefluorination Reactions”, Angew Chem Int Ed, 52:12 (2013), 3328
Moritz F. Kuehnel, Dieter Lentz, Thomas Braun, “Synthese fluorierter Bausteine durch Übergangsmetall‐vermittelte Hydrodefluorierungsreaktionen”, Angewandte Chemie, 125:12 (2013), 3412
David Breyer, Thomas Braun, Paul Kläring, “Synthesis and Reactivity of the Fluoro Complex trans-[Pd(F)(4-C5NF4)(iPr2PCH2CH2OCH3)2]: C–F Bond Formation and Catalytic C–F Bond Activation Reactions”, Organometallics, 31:4 (2012), 1417
Moritz F. Kuehnel, Philipp Holstein, Meike Kliche, Juliane Krüger, Stefan Matthies, Dominik Nitsch, Joseph Schutt, Michael Sparenberg, Dieter Lentz, “Titanium‐Catalyzed Vinylic and Allylic CF Bond Activation—Scope, Limitations and Mechanistic Insight”, Chemistry A European J, 18:34 (2012), 10701
Thomas R. Dugan, Jonathan M. Goldberg, William W. Brennessel, Patrick L. Holland, “Low-Coordinate Cobalt Fluoride Complexes: Synthesis, Reactions, and Production from C–F Activation Reactions”, Organometallics, 31:4 (2012), 1349
Thomas Braun, Falk Wehmeier, “C–F Bond Activation of Highly Fluorinated Molecules at Rhodium: From Model Reactions to Catalysis”, Eur J Inorg Chem, 2011:5 (2011), 613
Sergey A. Prikhod'ko, Nicolay Yu. Adonin, Valentin N. Parmon, “The ionic liquid [bmim]Br as an alternative medium for the catalytic cleavage of aromatic C–F and C–Cl bonds”, Tetrahedron Letters, 51:17 (2010), 2265
Alex D. Sun, Jennifer A. Love, “Cross coupling reactions of polyfluoroarenes via C–F activation”, Dalton Trans., 39:43 (2010), 10362
David Breyer, Thomas Braun, Anna Penner, “Isolation and reactivity of palladium hydrido complexes: intermediates in the hydrodefluorination of pentafluoropyridine”, Dalton Trans., 39:32 (2010), 7513
Hideki Amii, Kenji Uneyama, “C-F Bond Activation in Organic Synthesis”, Chem. Rev., 109:5 (2009), 2119
S. A. Prikhod'ko, N. Yu. Adonin, V. N. Parmon, “Reaction of pentafluoroacetanilide with zinc catalyzed by nickel complexes”, Russ Chem Bull, 58:11 (2009), 2304
N. Yu. Adonin, S. A. Prikhod'ko, V. V. Bardin, V. N. Parmon, “The first example of the ortho-directing effect of the weakly coordinating substituent [–BF3]– in the catalytic hydrodefluorination of the pentafluorophenyltrifluoroborate anion”, Mendeleev Commun., 19:5 (2009), 260–262
S. A. Prikhod'ko, N. Yu. Adonin, D. E. Babushkin, V. N. Parmon, “Highly regioselective nickel-catalyzed hydrodefluorination of pentafluoroacetanilide”, Mendeleev Commun., 18:4 (2008), 211–212
Thomas Braun, Daniel Noveski, Marcel Ahijado, Falk Wehmeier, “Hydrodefluorination of pentafluoropyridine at rhodium using dihydrogen: detection of unusual rhodium hydrido complexes”, Dalton Trans., 2007, no. 34, 3820
Vitalij D. Shteingarts, “Recent advances in practice and theory of polyfluoroarene hydrodehalogenation”, Journal of Fluorine Chemistry, 128:7 (2007), 797
Thomas Braun, Joseph Izundu, Andreas Steffen, Beate Neumann, Hans-Georg Stammler, “Reactivity of a palladium fluoro complex towards silanes and Bu3SnCHCH2: catalytic derivatisation of pentafluoropyridine based on carbon–fluorine bond activation reactions”, Dalton Trans., 2006, no. 43, 5118
Attila Sisak, Ottó Balázs Simon, The Handbook of Homogeneous Hydrogenation, 2006, 513