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Эта публикация цитируется в 2 научных статьях (всего в 2 статьях)
Stereoselective epoxidation of 4-fluoro-4-nitrocyclohexenes
V. E. Shambalova, R. V. Larkovich, S. A. Ponomarev, A. S. Aldoshin, K. A. Lyssenko, V. G. Nenajdenko
Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
Аннотация:
Novel fluorinated α-epoxycyclohexanes were synthesized in up to 96% yields by epoxidation of the Diels–Alder adducts of β-fluoro-β-nitrostyrenes and 2,3-dimethylbuta-1,3-diene. The epoxidation with m-chloroperoxybenzoic acid and
subsequent hydrolysis into diols were found to proceed in a highly stereoselective manner.
Ключевые слова:
organofluorine compounds, nitrostyrenes, Diels–Alder reaction, epoxidation, ring-opening, hydrolysis, diols.
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc428
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