Аннотация:
Upon treatment with SnCl2 in methanol at room temperature, 2,4,6-triazidopyridines undergo selective reduction of the γ-azido groups to give the corresponding 4-amino-2,6-diazidopyridines in high yields.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
S. V. Chapyshev, M. S. Platz, “Selective reduction of the azido groups of 2,4,6-triazidopyridines”, Mendeleev Commun., 11:2 (2001), 56–57
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc4215
https://www.mathnet.ru/rus/mendc/v11/i2/p56
Эта публикация цитируется в следующих 18 статьяx:
Silvia E. Loredo-Carrillo, Elisa Leyva, Matthew S. Platz, Agobardo Cárdenas-Chaparro, Antonio Martínez-Richa, “Thermolysis of 2-azido-3-(R-anilino)-1,4-naphthoquinones. Nitrene insertion versus hydrogen abstraction”, Tetrahedron Letters, 61:14 (2020), 151731
I. N. Bardasov, A. Yu. Alekseeva, D. L. Mikhailov, A. I. Ershova, O. V. Ershov, “Synthesis of 2,4-Diamino-6-arylpyridine-3,5-dicarbonitriles and Study of Their Optical Properties”, Russ J Org Chem, 56:8 (2020), 1501
Sergei V. Chapyshev, Alexander V. Chernyak, Evgeny N. Ushakov, “13C and 15N NMR spectra of high‐energy polyazidocyanopyridines”, Magnetic Reson in Chemistry, 55:2 (2017), 99
Sergei V. Chapyshev, Alexander V. Chernyak, Igor K. Yakushchenko, “Chemoselective Staudinger‐Phosphite Reaction on the Azido Groups of 2,4,6‐Triazido‐3,5‐dibromopyridine”, Journal of Heterocyclic Chem, 53:3 (2016), 970
Sergei Chapyshev, “Six-Membered Aromatic Polyazides: Synthesis and Application”, Molecules, 20:10 (2015), 19142
Sergei V. Chapyshev, Evgeny N. Ushakov, Alexander V. Chernyak, “15N NMR spectra and reactivity of 2,4,6‐triazidopyridines, 2,4,6‐triazidopyrimidine and 2,4,6‐triazido‐s‐triazine”, Magnetic Reson in Chemistry, 51:9 (2013), 562
S. V. Chapyshev, “Aromatic polyazides and high-spin nitrenes”, Russ Chem Bull, 60:7 (2011), 1274
S. V. Chapyshev, D. V. Korchagin, G. V. Shilov, S. M. Aldoshin, “Synthesis and structure of asymmetric 2,4,6-triazidopyridines”, Chem Heterocycl Comp, 47:7 (2011), 817
E. Ya. Misochko, A. V. Akimov, S. V. Chapyshev, “High resolution electron paramagnetic resonance spectroscopy of quintet pyridyl-2,6-dinitrene in solid argon: Magnetic properties and molecular structure”, The Journal of Chemical Physics, 128:12 (2008)
S. V. Chapyshev, V. F. Lavitskii, A. V. Akimov, E. Ya. Misochko, A. V. Shastin, D. V. Korchagin, G. V. Shilov, S. M. Aldoshin, “Photochemical generation of triplet—triplet nitrene pairs in aromatic diazide crystals”, Russ Chem Bull, 57:3 (2008), 524
E. Ya. Misochko, A. V. Akimov, V. F. Lavitskii, S. V. Chapyshev, “EPR spectroscopy of quintet 4-amino-3,5-dichloropyridine-2,6-diyldinitrene isolated in solid argon”, Russ Chem Bull, 56:12 (2007), 2364
S. V. Chapyshev, “Nucleophilic replacement of the azido groups by amines in 2,4,6-triazido-3-chloro-5-cyanopyridine”, Mendeleev Commun., 17:5 (2007), 287–288
Sergei V. Chapyshev, Paul M. Lahti, “Zero‐field splitting parameters of quintet 2,6‐dinitrenopyridines”, J of Physical Organic Chem, 19:10 (2006), 637
S. V. Chapyshev, “Photochemical synthesis and properties of quintet pyridyl-2,6-dinitrenes”, Russ Chem Bull, 55:9 (2006), 1593
Sergei V. Chapyshev, Richard Walton, Paul R. Serwinski, Paul M. Lahti, “Quintet State Electron Spin Resonance Spectra of Pyridyldinitrenes”, J. Phys. Chem. A, 108:32 (2004), 6643
S. V. Chapyshev, “Electronic absorption spectra of quintet and septet pyridylnitrenes”, Mendeleev Commun., 12:5 (2002), 168–170
Sergei V. Chapyshev, Matthew S. Platz, “ChemInform Abstract: Selective Reduction of the Azido Groups of 2,4,6‐Triazidopyridines.”, ChemInform, 32:33 (2001)
S. V. Chapyshev, P. R. Serwinski, “A new nitrene to carbene rearrangement upon photolysis of 4-amino-2,6-diazido-3,6-dichloropyridine”, Mendeleev Commun., 11:3 (2001), 92–94
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