Аннотация:
The condensation of dehydroacetic acid with RFCO2Et in the presence of LiH in THF afforded fluorine-containing 3-acetoacetyl- 4-hydroxy-6-methylpyrones, which underwent cyclization to 2-polyfluoroalkyl-7-methylpyrano[4,3-b]pyran-4,5-diones on treatment with concentrated sulfuric acid at room temperature.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
V. Ya. Sosnovskikh, B. I. Usachev, A. G. Blinov, M. I. Kodess, “New derivatives of dehydroacetic acid: synthesis of 2-polyfluoroalkyl-7-methylpyrano[4,3-b]pyran-4,5-diones”, Mendeleev Commun., 11:1 (2001), 36–38
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc4205
https://www.mathnet.ru/rus/mendc/v11/i1/p36
Эта публикация цитируется в следующих 7 статьяx:
María Victoria Cooke, Guillermo M. Chans, Gustavo A. Argüello, Walter José Peláez, “Photolysis, tautomerism and conformational analysis of dehydroacetic acid and a comparison with 2-hydroxyacetophenone and 2-acetyl-1,3-cyclohexanodione”, Heliyon, 6:7 (2020), e04457
Ranjana Aggarwal, Swati Walia, Chinu Rani, “Dehydroacetic Acid and Its Derivatives as Starting Synthons for Synthesis of Heterocyclic Compounds”, HETEROCYCLES, 94:7 (2017), 1197
Ahmed A. Fadda, Khaled M. Elattar, “Reactivity of dehydroacetic acid in organic synthesis”, Synthetic Communications, 46:1 (2016), 1
Boris I. Usachev, “2-(Trifluoromethyl)-4H-pyran-4-ones: Convenient, available and versatile building-blocks for regioselective syntheses of trifluoromethylated organic compounds”, Journal of Fluorine Chemistry, 172 (2015), 80
Vyacheslav Ya. Sosnovskikh, Fluorine in Heterocyclic Chemistry Volume 2, 2014, 211
Om Prakash, Ajay Kumar, Shiv P. Singh, “Synthesis of Heterocyclic Compounds from the Reactions of Dehydroacetic Acid (DHA) and Its Derivatives”, HETEROCYCLES, 63:5 (2004), 1193
Vyacheslav Ya. Sosnovskikh, Boris I. Usachev, Andrei G. Blinov, Mikhail I. Kodess, “ChemInform Abstract: New Derivatives of Dehydroacetic Acid: Synthesis of 2‐Polyfluoroalkyl‐7‐methylpyrano[4,3‐b]pyran‐4,5‐diones.”, ChemInform, 32:28 (2001)