Аннотация:
The oxidative dehydrogenation of ethane into ethylene using CO2 as an oxidant at temperatures of 650–750 °C was carried out over Fe/C, Cr/C and Fe–Cr/C catalysts deposited on a carbon support. Before and after the reaction the catalysts were investigated by X-ray powder diffraction (XRD), in situ magnetometry and transmission electron microscopy methods. The correlation between activity of Fe/C, Cr/C and Fe–Cr/C catalytic systems and their phase composition was established.
Ключевые слова:
oxidative dehydrogenation of ethane into ethylene, carbon dioxide, Fe/C catalyst, Cr/C catalyst, Fe–Cr/C catalyst, XRD, magnetometry, TEM.
Образец цитирования:
I. I. Mishanin, T. V. Bogdan, A. V. Smirnov, P. A. Chernavskii, N. N. Kuznetsova, V. I. Bogdan, “Formation of active phases of Fe/C, Cr/C and Fe–Cr/C catalysts in oxidative dehydrogenation of ethane”, Mendeleev Commun., 33:3 (2023), 422–424
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc416
https://www.mathnet.ru/rus/mendc/v33/i3/p422
Эта публикация цитируется в следующих 7 статьяx:
S. I. Pomogailo, E. G. Chepaikin, O. P. Tkachenko, O. N. Bubelo, R. I. Jussupkaliyeva, L. M. Kustov, Mendeleev Commun., 35:1 (2025), 1–10
Tanmayi Bathena, Truc Phung, Vijayakumar Murugesan, Konstantinos A. Goulas, Ajay S. Karakoti, Karthikeyan Ramasamy, “Transition metal oxides in CO2 driven oxidative dehydrogenation: Uncovering their redox properties”, Journal of CO2 Utilization, 84 (2024), 102848
M. P. Egorov, V. P. Ananikov, E. G. Baskir, S. E. Boganov, V. I. Bogdan, A. N. Vereshchagin, V. A. Vil', I. L. Dalinger, A. D. Dilman, O. L. Eliseev, S. G. Zlotin, E. A. Knyazeva, V. M. Kogan, L. O. Kononov, M. M. Krayushkin, V. B. Krylov, L. M. Kustov, V. V. Levin, B. V. Lichitsky, M. G. Medvedev, N. E. Nifantiev, O. A. Rakitin, A. M. Sakharov, I. V. Svitanko, G. A. Smirnov, A. Yu. Stakheev, M. A. Syroeshkin, A. O. Terent'ev, Yu. V. Tomilov, E. V. Tretyakov, I. V. Trushkov, L. L. Fershtat, V. A. Chaliy, V. Z. Shirinian, “Current trends in organic chemistry: contribution of the N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences”, Russ Chem Bull, 73:9 (2024), 2423
I. I. Mishanin, T. V. Bogdan, V. I. Bogdan, “The Influence of Pretreatment of Carbon Support on the Catalytic Activity of Fe–Cr Oxide Systems in the Oxidative Dehydrogenation of Ethane”, Solid Fuel Chem., 58:4 (2024), 265
I. I. Mishanin, T. V. Bogdan, T. V. Fedoseev, M. A. Skiba, P. A. Chernavsky, A. E. Koklin, K. I. Maslakov, V. I. Bogdan, “Influence of the Fe/Cr ratio on the catalytic activity of FeCr/C catalysts in the process of oxidative dehydrogenation of ethane”, Kat.v.prom., 24:4 (2024), 60
T. V. Bogdan, A. E. Koklin, N. V. Mashchenko, V. I. Bogdan, “Conversion of ethanol over calcium stannate catalyst under supercritical conditions”, Mendeleev Commun., 34:2 (2024), 218–220
T. V. Bogdan, A. N. Kalenchuk, A. E. Koklin, V. I. Bogdan, “Formation of Ptδ+/Pt0 active sites on Ni-Cr composites supported on carbon carrier in bicyclohexyl dehydrogenation”, Russ Chem Bull, 72:11 (2023), 2591
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