Аннотация:
The additions of a porphyrin cobalt complex diminished the rate of cross-linking copolymerization of ethylene glycol dimethacrylate (EGDMA) and styrene, shifted the autoacceleration process towards higher degrees of monomer conversions and modified the structure and properties of resulting cross-linked copolymers owing to catalytic chain transfer reaction, catalytic inhibition reaction and chain regeneration as a result of the reversible breakdown of a Co–C bond.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
S. V. Kurmaz, E. O. Perepelitsina, M. L. Bubnova, G. A. Estrina, V. P. Roshchupkin, “A cobalt(II)—porphyrin complex as a regulator of cross-linking radical copolymerization”, Mendeleev Commun., 12:1 (2002), 21–23
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc4073
https://www.mathnet.ru/rus/mendc/v12/i1/p21
Эта публикация цитируется в следующих 7 статьяx:
Niels M.B. Smeets, “Amphiphilic hyperbranched polymers from the copolymerization of a vinyl and divinyl monomer: The potential of catalytic chain transfer polymerization”, European Polymer Journal, 49:9 (2013), 2528
S. Slavin, K. McEwan, D.M. Haddleton, Polymer Science: A Comprehensive Reference, 2012, 249
Niels M. B. Smeets, Michael W. Freeman, Timothy F. L. McKenna, “Polymer Architecture Control in Emulsion Polymerization via Catalytic Chain Transfer Polymerization”, Macromolecules, 44:17 (2011), 6701
Johan P. A. Heuts, Niels M. B. Smeets, “Catalytic chain transfer and its derived macromonomers”, Polym. Chem., 2:11 (2011), 2407
S. V. Kurmaz, M. L. Bubnova, E. O. Perepelitsina, G. A. Estrina, “Control of crosslinking free-radical copolymerization of ethylene glycol dimethacrylate with alkyl methacrylates of various structures and macromolecular design of copolymers”, Polym. Sci. Ser. A, 48:7 (2006), 696
S. V. Kurmaz, E. O. Perepelitsina, “Cross-linking radical polymerization of di(meth)acrylates in the presence of cobalt(II) porphyrin”, Russ Chem Bull, 55:5 (2006), 835
S. V. Kurmaz, E. O. Perepelitsina, M. L. Bubnova, G. A. Estrina, “High-efficiency approach to control network structure formation in the cross-linking radical copolymerization of ethylene glycol dimethacrylate”, Mendeleev Commun., 14:3 (2004), 125–128
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