Аннотация:
The dimethylpalladium(II) PdMe2(tacn) complex supported with 1,4,7-triazacyclononane (tacn), obtained in situ via a reaction etween PdMe2(tmeda) and tacn reacts with methyl or ethyl iodide (RI) to form the most stable trialkyl palladium(IV) complexes [PdMe2R(tacn)]I.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
A. A. Sobanov, A. N. Vedernikov, G. Dyker, B. N. Solomonov, “Synthesis and reactivity of extremely thermally stable trialkylpalladium(IV) complexes supported with 1,4,7-triazacyclononane”, Mendeleev Commun., 12:1 (2002), 14–15
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc4069
https://www.mathnet.ru/rus/mendc/v12/i1/p14
Эта публикация цитируется в следующих 14 статьяx:
Andrei N. Vedernikov, Comprehensive Organometallic Chemistry IV, 2022, 783
Violaine Goudy, Arnaud Jaoul, Marie Cordier, Carine Clavaguéra, Grégory Nocton, “Tuning the Stability of Pd(IV) Intermediates Using a Redox Non-innocent Ligand Combined with an Organolanthanide Fragment”, J. Am. Chem. Soc., 139:31 (2017), 10633
Williamson N. Oloo, Peter Y. Zavalij, Andrei N. Vedernikov, “Palladium(IV) Monohydrocarbyls: Mechanistic Study of the Ligand-Enabled Oxidation of Palladium(II) Complexes with H2O2 in Water”, Organometallics, 32:19 (2013), 5601
Enrico T. Nadres, Gerson Ivan Franco Santos, Dmitry Shabashov, Olafs Daugulis, “Scope and Limitations of Auxiliary-Assisted, Palladium-Catalyzed Arylation and Alkylation of sp2 and sp3 C–H Bonds”, J. Org. Chem., 78:19 (2013), 9689
Julia R. Khusnutdinova, Fengrui Qu, Ying Zhang, Nigam P. Rath, Liviu M. Mirica, “Formation of the Palladium(IV) Complex [(Me3tacn)PdIVMe3]+ through Aerobic Oxidation of (Me3tacn)PdIIMe2 (Me3tacn = N,N′,N″-Trimethyl-1,4,7-triazacyclononane)”, Organometallics, 31:13 (2012), 4627
Julia R. Khusnutdinova, Nigam P. Rath, Liviu M. Mirica, “Dinuclear Palladium(III) Complexes with a Single Unsupported Bridging Halide Ligand: Reversible Formation from Mononuclear Palladium(II) or Palladium(IV) Precursors”, Angew Chem Int Ed, 50:24 (2011), 5532
Julia R. Khusnutdinova, Nigam P. Rath, Liviu M. Mirica, “Dinuclear Palladium(III) Complexes with a Single Unsupported Bridging Halide Ligand: Reversible Formation from Mononuclear Palladium(II) or Palladium(IV) Precursors”, Angewandte Chemie, 123:24 (2011), 5646
Dmitry Shabashov, Olafs Daugulis, “Auxiliary-Assisted Palladium-Catalyzed Arylation and Alkylation of sp2 and sp3 Carbon-Hydrogen Bonds”, J. Am. Chem. Soc., 132:11 (2010), 3965
José Vicente, Aurelia Arcas, Francisco Juliá-Hernández, Delia Bautista, “Quantitative synthesis and full characterization of the first isolated and stable pincer palladium(iv) complexes. Quantitative and regioselective synthesis of the C–X (X = Cl, Br) reductive elimination products”, Chem. Commun., 46:38 (2010), 7253
S. Masoud Nabavizadeh, Sepideh Habibzadeh, Mehdi Rashidi, Richard J. Puddephatt, “Oxidative Addition of Ethyl Iodide to a Dimethylplatinum(II) Complex: Unusually Large Kinetic Isotope Effects and Their Transition-State Implications”, Organometallics, 29:23 (2010), 6359
Williamson Oloo, Peter Y. Zavalij, Jing Zhang, Eugene Khaskin, Andrei N. Vedernikov, “Preparation and C-X Reductive Elimination Reactivity of Monoaryl PdIV-X Complexes in Water (X = OH, OH2, Cl, Br)”, J. Am. Chem. Soc., 132:41 (2010), 14400
Petr Sehnal, Richard J. K. Taylor, Ian J. S. Fairlamb, “Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis”, Chem. Rev., 110:2 (2010), 824
Dmitry V. Khoroshun, Djamaladdin G. Musaev, Keiji Morokuma, “Electronic reorganization: Origin of sigma trans promotion effect”, J Comput Chem, 28:1 (2007), 423
D. N. Laikov, Yu. A. Ustynyuk, “PRIRODA-04: a quantum-chemical program suite. New possibilities in the study of molecular systems with the application of parallel computing”, Russ Chem Bull, 54:3 (2005), 820
Обратная связь: