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Эта публикация цитируется в 5 научных статьях (всего в 5 статьях)
The first chiral derivatives of 1-boraadamantane
M. E. Gurskiia, V. A. Ponomareva, K. A. Lyssenkob, M. Yu. Antipinb, Ph. Renaudc, Yu. N. Bubnovb
a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
c Department of Chemistry and Biochemistry, University of Bern, Bern, Switzerland
Аннотация:
Both (S)-(+)- [(S)-5] and (R)-(–)-2-methyl-1-boraadamantane [(R)-5] were isolated in 96% and 92% ee, respectively, by the crystallization of corresponding (S)-(–)- and (R)-(+)-phenylethylamine adducts from hexane and transformed into optically active 1-hydroxy-2-methyladamantanes by the carbonylation–oxidation sequence.
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https://www.mathnet.ru/rus/mendc3983
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