Аннотация:
Both (S)-(+)- [(S)-5] and (R)-(−)-2-methyl-1-boraadamantane [(R)-5] were isolated in 96% and 92% ee, respectively, by the crystallization of corresponding (S)-(−)- and (R)-(+)-phenylethylamine adducts from hexane and transformed into optically active 1-hydroxy-2-methyladamantanes by the carbonylation–oxidation sequence.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
M. E. Gurskii, V. A. Ponomarev, K. A. Lyssenko, M. Yu. Antipin, Ph. Renaud, Yu. N. Bubnov, “The first chiral derivatives of 1-boraadamantane”, Mendeleev Commun., 13:3 (2003), 121–123