Аннотация:
For the first time, spontaneous resolution of trans-dihydroxyimidazolidin-2-one 1a was performed and racemisation of (–)-1a was studied; regiospecific reaction of 1a–c with aminoguanidine resulted in derivatives 2a–c; compound 2b was also shown to undergo spontaneous resolution, and the absolute configuration (4R,5R) of (–)-2b crystals was established by X-ray diffraction analysis.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
A. N. Kravchenko, G. K. Kadorkina, A. S. Sigachev, E. Yu. Maksareva, K. A. Lyssenko, P. A. Belyakov, O. V. Lebedev, O. N. Kharybin, N. N. Makhova, R. G. Kostyanovsky, “Spontaneous resolution in the imidazolidin-2-one series”, Mendeleev Commun., 13:3 (2003), 114–116
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc3980
https://www.mathnet.ru/rus/mendc/v13/i3/p114
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O. A. Lodochnikova, Yu. K. Voronina, L. Z. Latypova, D. B. Krivolapov, A. R. Kurbangalieva, I. A. Litvinov, “Crystallization of racemic 4-arylsulfonyl-2(5H)-furanones: reproducibility of homochiral associates, conditions for the spontaneous resolution of enantiomers and the formation of racemic compounds, the role of intermolecular interactions”, Russ Chem Bull, 62:5 (2013), 1218
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