Reactions of N,N-bis(silyloxy)enamines with sulfur-centered and sulfur-stabilised electrophiles

The coupling of N,N-bis(silyloxy)enamines with arylsulfenyl chlorides and episulfonium cations proceeds as an electrophilic attack at the β-carbon atoms of N,N-bis(silyloxy)enamines and affords functionalised aliphatic compounds.