Аннотация:
A chiral cobalt(III) complex of a Schiff base derived from (R)-tryptophan and salicylaldehyde catalysed asymmetric trimethyl-silylcyanation of benzaldehyde at ambient temperature and a 20:1 substrate/catalyst ratio with the formation of enantiomerically enriched mandelonitrile (ee up to 77%).
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
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Wei Fang, Bing-Bing Sun, Shi-Cheng Qin, Li-Ping Fang, Xin-Ran Yu, Hua-Jie Jiang, Jie Yu, “Enantioselective Access to Chiral 2,5-Diketopiperazines via Stereogenic-at-Cobalt(III)-Catalyzed Ugi-4CRs/Cyclization Sequences”, J. Org. Chem., 88:22 (2023), 16024
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Olga V. Khromova, Mikhail A. Emelyanov, Alexander F. Smol'yakov, Ivan V. Fedyanin, Victor I. Maleev, Vladimir A. Larionov, “Family of Well-Defined Chiral-at-Cobalt(III) Complexes as Metal-Templated Hydrogen-Bond-Donor Catalysts: Effect of Chirality at the Metal Center on the Stereochemical Outcome of the Reaction”, Inorg. Chem., 61:14 (2022), 5512
Mikhail A. Emelyanov, Nadezhda V. Stoletova, Alexander F. Smol'yakov, Mikhail M. Il'in, Victor I. Maleev, Vladimir A. Larionov, “Synthesis and a Catalytic Study of Diastereomeric Cationic Chiral-at-Cobalt Complexes Based on (R,R)-1,2-Diphenylethylenediamine”, Inorg. Chem., 60:18 (2021), 13960
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Tat'yana F. Savel'yeva, Olga V. Khromova, Vladimir A. Larionov, Alexander F. Smol'yakov, Ivan V. Fedyanin, Yuri N. Belokon, Victor I. Maleev, “Expanding the Family of Octahedral Chiral-at-Metal Cobalt(III) Catalysts by Introducing Tertiary Amine Moiety into the Ligand”, Catalysts, 11:2 (2021), 152
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Thomas Cruchter, Michael G. Medvedev, Xiaodong Shen, Thomas Mietke, Klaus Harms, Michael Marsch, Eric Meggers, “Asymmetric Nucleophilic Catalysis with an Octahedral Chiral-at-Metal Iridium(III) Complex”, ACS Catal., 7:8 (2017), 5151
Lilu Zhang, Eric Meggers, “Stereogenic‐Only‐at‐Metal Asymmetric Catalysts”, Chemistry — An Asian Journal, 12:18 (2017), 2335
Eric Meggers, “Exploiting Octahedral Stereocenters: From Enzyme Inhibition to Asymmetric Photoredox Catalysis”, Angew Chem Int Ed, 56:21 (2017), 5668
Eric Meggers, “Ausnutzung oktaedrischer Stereozentren: von Enzymhemmung bis hin zu asymmetrischer Photoredoxkatalyse”, Angewandte Chemie, 129:21 (2017), 5760
Yuri A. Rulev, Vladimir A. Larionov, Anastasia V. Lokutova, Margarita A. Moskalenko, Ol'ga L. Lependina, Victor I. Maleev, Michael North, Yuri N. Belokon, “Chiral Cobalt(III) Complexes as Bifunctional Brønsted Acid–Lewis Base Catalysts for the Preparation of Cyclic Organic Carbonates”, ChemSusChem, 9:2 (2016), 216
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