Аннотация:
The reaction of the potassium salt of 3-phenyl-5(Z)-(pyridin-2-ylmethylene)-2-thioxoimidazolidin-4-one (KL) with CoCl2·6H2O in MeCN results in formation of the neutral complex CoIIL2. According to single-crystal X-ray analysis, the CoII centre is coordinated to four nitrogen atoms of two organic ligands and has a distorted tetrahedral geometry. This complex undergoes electrochemical reduction with consequent two reversible and one quasi-reversible stages.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
A. G. Majouga, E. K. Beloglazkina, S. Z. Vatsadze, A. A. Moiseeva, F. S. Moiseev, K. P. Butin, N. V. Zyk, “The first example of a reversibly reducible CoII complex with an anionic 2-thiohydantoin-type ligand”, Mendeleev Commun., 15:2 (2005), 48–50
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc3670
https://www.mathnet.ru/rus/mendc/v15/i2/p48
Эта публикация цитируется в следующих 11 статьяx:
Maksim Kukushkin, Vladimir Novotortsev, Vadim Filatov, Yan Ivanenkov, Dmitry Skvortsov, Mark Veselov, Radik Shafikov, Anna Moiseeva, Nikolay Zyk, Alexander Majouga, Elena Beloglazkina, “Synthesis and Biological Evaluation of S-, O- and Se-Containing Dispirooxindoles”, Molecules, 26:24 (2021), 7645
N. I. Vorozhtsov, L. A. Sviridova, O. S. Grigorkevich, D. D. Korablina, E. K. Beloglazkina, A. G. Majouga, N. V. Zyk, “Synthesis 5-(pyrazolin-3-ylmethylidene)-2-thiohydantoins and 2-alkylsulfanyl-5-(pyrazolin-3-ylmethylidene)-3,5-dihydro-4H-imidazol-4-ones”, Russ Chem Bull, 66:3 (2017), 506
Elena K. Beloglazkina, Nikolai I. Vorozhtsov, Lyudmila A. Sviridova, Oksana S. Grigorkevich, Diana D. Korablina, Anna A. Moiseeva, Nikolay V. Zyk, Alexander G. Majouga, “The first example of Cu(I) complex with 5-pyrazolyl-2-thioxotetrahydro-4H-imidazol-4-one: Synthesis and structural characterization”, Inorganic Chemistry Communications, 71 (2016), 86
Alexander G. Majouga, Elena K. Beloglazkina, Anna A. Moiseeva, Olga V. Shilova, Eugeniy A. Manzheliy, Maria A. Lebedeva, E. Stephen Davies, Andrei N. Khlobystov, Nikolay V. Zyk, “Cleavage of the C–S bond with the formation of a binuclear copper complex with 2-thiolato-3-phenyl-5-(pyridine-2-ylmethylene)-3,5-dihydro-4H-imidazole-4-one. A new mimic of the active site of N2O reductase”, Dalton Trans., 42:18 (2013), 6290
Elena K. Beloglazkina, Alexander G. Majouga, Andrei V. Mironov, Anna V. Yudina, Anna A. Moiseeva, Maria A. Lebedeva, Andrei N. Khlobystov, Nikolai V. Zyk, “Synthesis, X-ray crystallography and electrochemistry of three novel copper complexes with imidazole-containing hydantoin and thiohydantoins”, Polyhedron, 63 (2013), 15
Elena K. Beloglazkina, Alexander G. Majouga, Anna A. Moiseeva, Nikolai V. Zyk, “Coordination Compounds of S- and Se-Containing Organic Ligands as Catalysts of Oxidation Reaction Under N2O Action”, Phosphorus, Sulfur, and Silicon and the Related Elements, 188:4 (2013), 377
A. N. Chernysheva, T. S. Vorob'eva, E. K. Beloglazkina, A. G. Majouga, A. A. Moiseeva, N. V. Zyk, “Synthesis and electrochemical studies of CoII complex with 3-phenyl-5(Z)-(pyridin-2-ylmethylidene)-2-selenohydantoin”, Russ Chem Bull, 61:9 (2012), 1828
M. Yu. Steklov, A. N. Chernysheva, R. L. Antipin, A. G. Majouga, E. K. Beloglazkina, A. A. Moiseeva, E. D. Strel'tsova, N. V. Zyk, “Synthesis and coordinating properties of 5-phenyl- and 5-pyridylmethylidene-substituted 2-selenohydantoines and 2-selenoimidazol-4-ones”, Russ Chem Bull, 61:6 (2012), 1182
E. K. Beloglazkina, A. G. Majouga, E. A. Manzhelii, N. V. Zyk, N. S. Zefirov, “2-Thioxo-tetrahydro-4H-imidazol-4-ones, 2-alkylthio-3,5-dihydro-4H-imidazol-4-ones and their coordination compounds with transition metal ions”, Ref. J. Chem., 1:4 (2011), 309
E. K. Beloglazkina, A. G. Majouga, A. A. Moiseeva, M. G. Tsepkov, N. V. Zyk, “5-[2-(Methylthio)ethyl]-3-phenyl-2-thioxoimidazolidin-4-one and its complexes with transition metals (CoII, NiII, and CuII). Synthesis and electrochemical investigation”, Russ Chem Bull, 56:2 (2007), 351
E. K. Beloglazkina, A. G. Majouga, I. V. Yudin, N. A. Frolova, N. V. Zyk, V. D. Dolzhikova, A. A. Moiseeva, R. D. Rakhimov, K. P. Butin, “5-(Pyridylmethylidene)-substituted 2-thiohydantoins and their complexes with CuII, NiII, and CoII: Synthesis, electrochemical study, and adsorption on the cystamine-modified gold surface”, Russ Chem Bull, 55:6 (2006), 1015
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