Аннотация:
Tris[2-(phenylthio)ethyl]phosphine oxide reacts with sodium amide to afford trivinylphosphine oxide in a good yield. The reaction involves the generation of phosphoryl-stabilised carbanions, which further eliminate benzene thiolate anions.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
N. K. Gusarova, N. A. Chernysheva, S. N. Arbuzova, M. V. Bogdanova, N. I. Ivanova, A. A. Kudryavtsev, B. A. Trofimov, “Thiol elimination from tris[2-(phenylthio)ethyl]phosphine oxide: a convenient route to trivinylphosphine oxide”, Mendeleev Commun., 16:1 (2006), 31
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc3505
https://www.mathnet.ru/rus/mendc/v16/i1/p31
Эта публикация цитируется в следующих 5 статьяx:
Khalifah A. Salmeia, Akef T. Afaneh, Reem R. Habash, Antonia Neels, “Trivinylphosphine Oxide: Synthesis, Characterization, and Polymerization Reactivity Investigated Using Single-Crystal Analysis and Density Functional Theory”, Molecules, 28:16 (2023), 6097
Sergey V. Fedorov, Leonid B. Krivdin, Yury Yu. Rusakov, Nataliya A. Chernysheva, Valentina L. Mikhailenko, “Trivinylphosphine and trivinylphosphine chalcogenides: stereochemical trends of 31P1H spin-spin coupling constants”, Magn. Reson. Chem., 48:S1 (2010), S48
S. V. Fedorov, Yu. Yu. Rusakov, L. B. Krivdin, N. V. Istomina, S. N. Arbuzova, S. F. Malysheva, “Theoretical conformational analysis of unsaturated phospines and phosphinechalcogenides”, Russ J Org Chem, 45:5 (2009), 667
N. K. Gusarova, S. I. Verkhoturova, T. I. Kazantseva, N. A. Chernysheva, V. L. Mikhailenko, S. F. Malysheva, B. A. Trofimov, “Nucleophilic addition of phosphine to vinyl sulfoxides”, Russ J Gen Chem, 78:5 (2008), 1011
Nina K. Gusarova, Nataliya A. Chernysheva, Svetlana N. Arbuzova, Maria V. Bogdanova, Nina I. Ivanova, Andrei A. Kudryavtsev, Boris A. Trofimov, “Thiol Elimination from Tris[2‐(phenylthio)ethyl]phosphine Oxide: A Convenient Route to Trivinylphosphine Oxide.”, ChemInform, 37:27 (2006)
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