Аннотация:
In the superbase catalytic systems ButOK/NMP, AmtOCs/NMP and KOH/DMSO, methanol readily adds to propyne and allene at 100–120 °C and atmospheric pressure to afford 2-methoxypropene in 80–97% yield with 75–94% methanol conversion.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
B. A. Trofimov, L. A. Oparina, N. K. Gusarova, M. Ya. Khil'ko, L. N. Parshina, J. Henkelmann, “Superbase-catalysed addition of methanol to propyne and allene: an expedient synthesis of 2-methoxypropene”, Mendeleev Commun., 16:1 (2006), 13–14
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc3496
https://www.mathnet.ru/rus/mendc/v16/i1/p13
Эта публикация цитируется в следующих 5 статьяx:
Damir Z. Absalyamov, Nadezhda M. Vitkovskaya, Vladimir B. Orel, Elena Yu. Schmidt, Boris A. Trofimov, “Quantum‐Chemical Insight into Self‐Organization of Complex Molecules from Acetylene and Anilines Catalyzed by Superbase KOH/DMSO: One‐Pot Cascade Assembly of 1,3‐Bis(arylamines)”, Asian J Org Chem, 12:4 (2023)
Lyudmila A. Grishchenko, Lidiya N. Parshina, Lyudmila I. Larina, Lyudmila A. Belovezhets, Igor V. Klimenkov, Alexander Yu. Ustinov, Boris A. Trofimov, “Arabinogalactan propargyl ethers: Au-catalysed hydroamination by imidazols”, Carbohydrate Polymers, 246 (2020), 116638
Boris A. Trofimov, Ludmila A. Oparina, Olga A. Tarasova, Alexander V. Artem'ev, Vladimir B. Kobychev, Yuriy V. Gatilov, Alexander I. Albanov, Nina K. Gusarova, “Tuneable superbase-catalyzed vinylation of α-hydroxyalkylferrocenes with alkynes”, Tetrahedron, 70:35 (2014), 5954
Alex S. Ionkin, William J. Marshall, Brian M. Fish, “Highly Sterically Hindered Olefins: A Case of E- and Z-Di-tert-butyl α,β-Unsaturated Acids”, Org. Lett., 10:11 (2008), 2303
Boris A. Trofimov, Ludmila A. Oparina, Nina K. Gusarova, Marina Ya. Khil'ko, Lidiya N. Parshina, Jochem Henkelmann, “Superbase‐Catalyzed Addition of Methanol to Propyne and Allene: An Expedient Synthesis of 2‐Methoxypropene.”, ChemInform, 37:27 (2006)
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