Аннотация:
A DFT study of ethane activation over cadmium exchanged ZSM-5 zeolite shows that the interaction of C2H6 with the Cd2+ sites results in a strongly perturbed molecular adsorption leading to heterolytic cleavage of the C–H bond with a moderate activation barrier.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
E. A. Pidko, R. A. van Santen, “Activation of light alkanes over Cd2+ ions in ZSM-5 zeolite: a theoretical study”, Mendeleev Commun., 17:2 (2007), 68–70
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc3379
https://www.mathnet.ru/rus/mendc/v17/i2/p68
Эта публикация цитируется в следующих 8 статьяx:
Haifeng Tian, Duoyong Shi, Lei Yu, Fei Zha, Xiaohua Tang, Yue Chang, Xiaojun Guo, “Transformation of methanol to trimethylbenzene catalyzed by cadmium modified HZSM-5 zeolites”, Reac Kinet Mech Cat, 135:1 (2022), 333
Akira Oda, Kyoichi Sawabe, Takahiro Ohkubo, Yasushige Kuroda, “Identification of a Stable Ozonide Ion Bound to a Single Cadmium Site within the Zeolite Cavity”, J. Phys. Chem. C, 126:1 (2022), 261
Hao Chen, Yao Jun Zhang, Pan Yang He, Chan Juan Li, “Synthesis, characterization and modification of monolithic ZSM-5 from geopolymer for CO2 capture: Experiments and DFT calculations”, Energy, 179 (2019), 422
Yongkun Zhang, Yixin Qu, Deliang Wang, Xiao Cheng Zeng, Jidong Wang, “Cadmium Modified HZSM-5: A Highly Efficient Catalyst for Selective Transformation of Methanol to Aromatics”, Ind. Eng. Chem. Res., 56:44 (2017), 12508
R. Hercigonja, V. Rac, V. Rakic, A. Auroux, “Enthalpy–entropy compensation for n-hexane adsorption on HZSM-5 containing transition metal ions”, The Journal of Chemical Thermodynamics, 48 (2012), 112
Evgeny A. Pidko, Emiel J. M. Hensen, Rutger A. van Santen, “Self-organization of extraframework cations in zeolites”, Proc. R. Soc. A., 468:2143 (2012), 2070
Evgeny A. Pidko, Emiel J. M. Hensen, Rutger A. van Santen, “Dehydrogenation of Light Alkanes over Isolated Gallyl Ions in Ga/ZSM-5 Zeolites”, J. Phys. Chem. C, 111:35 (2007), 13068
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