Аннотация:
The complex [(Z-PhCH=CH)3P]2PdCl2 synthesized from tris(Z-styryl)phosphine and PdCl2 (DMF, 90 °C, 15min, yield 50%) is an active catalyst in the Sonogashira reaction (coupling between 1-ethynyl-4-nitrobenzene and 1-iodoanthra-9,10-quinone) and its activity is comparable with that of the complex [Ph3P]2PdCl2, the most common catalyst for this type of reactions.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
B. A. Trofimov, S. F. Vasilevskii, N. K. Gusarova, S. F. Malysheva, D. S. Baranov, V. I. Mamatyuk, Yu. V. Gatilov, “Complex of tris(Z-styryl)phosphine with PdCl2 as a new catalyst for the Sonogashira reaction”, Mendeleev Commun., 18:6 (2008), 318–319
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc3341
https://www.mathnet.ru/rus/mendc/v18/i6/p318
Эта публикация цитируется в следующих 12 статьяx:
V. V. Sharutin, V. S. Senchurin, “Palladium Complexes [Ph3PCH2C(O)Me][PdCDmso-S)] and [Ph4Sb(Dmso-O)][PdBr3(Dmso-S)]: Synthesis and Structures”, Russ J Coord Chem, 49:7 (2023), 453
S. F. Vasilevsky, A. A. Stepanov, “Alkyl, Aryl, and Hetaryl Acetylenes: Highly Reactive Multifunctional Compounds (A Review)”, Russ J Gen Chem, 93:10 (2023), 2417
S. F Vasilevsky, A. A Stepanov, “Alkyl, aryl and hetaryl acetylenes - highly reactive multifunctional compounds (a review)”, Žurnal obŝej himii, 93:10 (2023), 1479
V. V. Sharutin, O. K. Sharutina, V. S. Senchurin, “Palladium Complexes [Ph3PEt][PdBr3(DMSO)], [Ph3PCH2OMe][PdBr3(DMSO)], [Ph3PC5H9-cyclo][PdBr3(DMSO)], and [Ph3PCH2CH=CHCH2PPh3][PdBr3(DMSO)]2: Synthesis and Structure”, Russ J Coord Chem, 48:9 (2022), 586
С. Ф. Василевский, А. А. Степанов, “Методы синтеза, реакционная способность и прикладные аспекты ацетиленовых производных хинонов и продуктов”, Усп. хим., 91:1 (2022), RCR5020 ; S. F. Vasilevskii, A. A. Stepanov, “Acetylene derivatives of quinones and their transformation products: synthesis, reactivity and applied aspects”, Russian Chem. Reviews, 91:1 (2022), RCR5020
Н. К. Гусарова, Б. А. Трофимов, “Химия фосфорорганических соединений на основе элементного фосфора: достижения и горизонты”, Усп. хим., 89:2 (2020), 225–249; N. K. Gusarova, B. A. Trofimov, “Organophosphorus chemistry based on elemental phosphorus: advances and horizons”, Russian Chem. Reviews, 89:2 (2020), 225–249
Anastasiya I. Govdi, Sergey F. Vasilevsky, Svetlana F. Malysheva, Olga N. Kazheva, Oleg A. Dyachenko, Vladimir A. Kuimov, “Tri(1‐naphthyl)phosphine as a ligand in palladium‐free Sonogashira cross‐coupling of arylhalogenides with acetylenes”, Heteroatom Chemistry, 29:4 (2018)
N. K. Gusarova, A. O. Sutyrina, E. A. Matveeva, I. V. Sterkhova, V. I. Smirnov, B. A. Trofimov, “One-Pot Chlorine-Free Synthesis of Chiral Organophosphorus Compounds from Elemental Phosphorus and α-Methylstyrene Dimer”, Dokl Chem, 478:1 (2018), 5
Б. А. Трофимов, Е. Ю. Шмидт, “Реакции ацетиленов в суперосновных средах — итоги последних лет”, Усп. хим., 83:7 (2014), 600–619; B. A. Trofimov, E. Yu. Schmidt, “Reactions of acetylenes in superbasic media. Recent advances”, Russian Chem. Reviews, 83:7 (2014), 600–619
N. K. Gusarova, S. I. Verkhoturova, T. I. Kazantseva, V. L. Mikhailenko, S. N. Arbuzova, B. A. Trofimov, “Free-radical addition of phosphine to vinyl ethers: atom-economic synthesis of tris(2-organyloxyethyl)phosphines and their derivatives”, Mendeleev Commun., 21:1 (2011), 17–18
Boris A. Trofimov, Sergei F. Vasilevsky, Nina K. Gusarova, Svetlana F. Malysheva, Denis S. Baranov, Victor I. Mamatyuk, Yurii V. Gatilov, “ChemInform Abstract: Complex of Tris(Z‐styryl)phosphine with PdCl2 as a New Catalyst for the Sonogashira Reaction.”, ChemInform, 40:14 (2009)
B. A. Trofimov, N. K. Gusarova, “Elemental phosphorus in strongly basic media as phosphorylating reagent: a dawn of halogen-free ‘green' organophosphorus chemistry”, Mendeleev Commun., 19:6 (2009), 295–302
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