Аннотация:
Cyclic voltammetry and controlled potential electrolysis were used to show that radical anions of 2- and 4-nitrophenylhydroxylamines electrochemically generated in a 0.1M Bu4NClO4 solution in DMF undergo protonation with the starting compounds (self-protonation) followed by the formation of the corresponding nitroanilines.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
M. A. Syroeshkin, A. S. Mendkovich, L. V. Mikhalchenko, A. I. Rusakov, V. P. Gul'tyai, “Self-protonation upon the electroreduction of 2- and 4-nitrophenylhydroxylamines in aprotic media”, Mendeleev Commun., 19:5 (2009), 258–259
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc3190
https://www.mathnet.ru/rus/mendc/v19/i5/p258
Эта публикация цитируется в следующих 7 статьяx:
A. S. Mendkovich, A. I. Rusakov, “REACTIVITY OF ANION RADICAL AND DIANION OF ORGANIC COMPOUNDS (REVIEW)”, Èlektrohimiâ, 59:12 (2023), 753
A. S. Mendkovich, A. I. Rusakov, “Reactivity of Radical Anions and Dianions of Organic Compounds: A Review”, Russ J Electrochem, 59:12 (2023), 999
R. S. Begunov, V. O. Sakulina, M. A. Syroeshkin, E. A. Saverina, A. A. Sokolov, M. E. Minyaev, “Electroreductive heterocyclization of ortho-piperidino substituted nitro(het)arenes”, Mendeleev Commun., 30:5 (2020), 633–635
Andrey S. Mendkovich, Mikhail A. Syroeshkin, Darya V. Nasybullina, Mikhail N. Mikhailov, Vadim P. Gultyai, Alexander I. Rusakov, “Electroreduction mechanism of N-phenylhydroxylamines in aprotic solvents: N-(2-nitrophenyl)- and N-(3-nitrophenyl)hydroxylamines”, Electrochimica Acta, 238 (2017), 9
Andrey S. Mendkovich, Mikhail A. Syroeshkin, Darya V. Ranchina, Mikhail N. Mikhailov, Vadim P. Gultyai, Alexander I. Rusakov, “Electroreduction mechanism of N-arylhydroxylamines in aprotic solvents: N-(4-nitrophenyl)hydroxylamine”, Journal of Electroanalytical Chemistry, 728 (2014), 60
Andrey S. Mendkovich, Mikhail A. Syroeshkin, Ludmila V. Mikhalchenko, Mikhail N. Mikhailov, Alexander I. Rusakov, Vadim P. Gul'tyai, “Integrated Study of the Dinitrobenzene Electroreduction Mechanism by Electroanalytical and Computational Methods”, International Journal of Electrochemistry, 2011 (2011), 1
M. A. Syroeshkin, L. V. Mikhalchenko, M. Yu. Leonova, A. S. Mendkovich, A. I. Rusakov, V. P. Gul'tyai, “Electrochemically initiated transformation of 4-nitrophenylhydroxylamine into 4,4′-dinitroazobenzene”, Mendeleev Commun., 21:1 (2011), 26–28