Аннотация:
Cyanide reacts with tetracyanomethane towards the tricyanomethyl anion via cyanophilic substitution; this is suggested by nitrogen isotope-labeling experiments and proven by density functional calculations at OLYP/TZ2P.
Образец цитирования:
F. M. Bickelhaupt, C. Fonseca Guerra, N. S. Zefirov, “C(CN)5–: transition state or intermediate?”, Mendeleev Commun., 20:2 (2010), 72–73
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc2993
https://www.mathnet.ru/rus/mendc/v20/i2/p72
Эта публикация цитируется в следующих 6 статьяx:
Weam A. O. Altalhi, Bun Chan, Richard A. J. O'Hair, “Methide Affinity Scale: Key Thermodynamic Data Underpinning Catalysis, Organic Synthesis, and Organometallic and Polymer Chemistry”, J. Phys. Chem. A, 128:6 (2024), 977
Nery Villegas-Escobar, Javier Martínez, Ricardo A. Matute, Sebastián Saltarini, Constantin G. Daniliuc, Lutz H. Gade, René S. Rojas, “Trapping an unusual pentacoordinate carbon atom in a neutral trialuminum complex”, Chem. Commun., 57:80 (2021), 10327
Trevor A. Hamlin, Marcel Swart, F. Matthias Bickelhaupt, “Nucleophilic Substitution (SN2): Dependence on Nucleophile, Leaving Group, Central Atom, Substituents, and Solvent”, ChemPhysChem, 19:11 (2018), 1315
William C. McKee, Jay Agarwal, Henry F. Schaefer, Paul von R. Schleyer, “Covalent Hypercoordination: Can Carbon Bind Five Methyl Ligands?”, Angew Chem Int Ed, 53:30 (2014), 7875
William C. McKee, Jay Agarwal, Henry F. Schaefer, Paul von R. Schleyer, “Covalent Hypercoordination: Can Carbon Bind Five Methyl Ligands?”, Angewandte Chemie, 126:30 (2014), 8009
Henk M. Buck, “Molecular model studies based on ab initio calculations of nucleophilic and electrophilic addition‐substitution reactions focused on carbon–halogen compounds”, Int J of Quantum Chemistry, 111:15 (2011), 4472
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