Аннотация:
The reactions of ‘double’ donor–acceptor cyclopropanes containing a p- or m-phenylene moiety with alkenes or dienes in the presence of GaCl3 comprise formation of gallium 1,2-zwitterionic intermediates, the structure of final products being substrate dependent. In contrast to the para-or meta-isomers, reaction of 2,2'-(1,2-phenylene)bis(cyclopropane-1,1-dicarboxylate) does not involve alkene and affords isomeric tricyclo[6.2.2.02,7]dodeca-2,4,6-triene-9,9,11,11-tetra-carboxylate, a product of intramolecular rearrangement.
Образец цитирования:
D. A. Knyazev, M. A. Belaya, A. D. Volodin, A. A. Korlyukov, R. A. Novikov, Yu. V. Tomilov, “Gallium trichloride-mediated reactions of ‘double’ donor–acceptor cyclopropanes with alkenes and dienes”, Mendeleev Commun., 33:1 (2023), 30–33
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc298
https://www.mathnet.ru/rus/mendc/v33/i1/p30
Эта публикация цитируется в следующих 3 статьяx:
Fatemeh Doraghi, Somaye Karimian, Omid Hosseinchi Qareaghaj, Mohammad Javad Karimi, Bagher Larijani, Mohammad Mahdavi, “Recent advances in ring-opening reactions of 2-substituted donor-acceptor cyclopropanes under metal catalysis”, Journal of Organometallic Chemistry, 1005 (2024), 122963
Yu. A. Volkova, M. A. Boichenko, V. V. Shorokhov, S. S. Zhokhov, I. A. Andreev, N. K. Ratmanova, I. V. Trushkov, O. A. Ivanova, “Competition of (3+2) annulation and (3+2) cycloaddition in the reaction of alkenes with donor-acceptor cyclopropanes”, Russ Chem Bull, 73:5 (2024), 1237
П. Г. Сергеев, Р. А. Новиков, Ю. В. Томилов, “Реакции циклизации циклопропановых производных с сопряженными карбо- и гетеросистемами”, Усп. хим., 93:3 (2024), RCR5111 ; P. G. Sergeev, R. A. Novikov, Yu. V. Tomilov, “Cyclization reactions of cyclopropane derivatives with conjugated carbo- and heterosystems”, Russian Chem. Reviews, 93:3 (2024), RCR5111
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