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Эта публикация цитируется в 6 научных статьях (всего в 6 статьях)
Carbamide-containing complexes of lanthanides:
competition of hydrogen bonding and polyiodide ion formation
L. Yu. Alikberovaa, K. A. Lyssenkob, N. S. Rukka, A. I. Mytarevaa
a M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Аннотация:
The carbamide complexes of lanthanide polyiodoiodates [Tm(ur)7][I3]3·2I2, [Yb(ur)6][I3]3 and [Lu(ur)6][I3]3 [ur is O=C(NH2)2] have been synthesized and structurally characterized. The structure-forming role of the pentaiodide ions taking part in the formation of extended channels 10–12 Å in diameter with incorporated hepta(carbamide)thulium cations combined to one another into infinite columns due to H-bonding, or the triiodide ions forming lace-like net with isolated hexa(carbamide)ytterbium(III) or hexa(carbamide) lutetium(III) cations located in the net holes has been revealed.
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https://www.mathnet.ru/rus/mendc2917
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