Аннотация:
P*-Chiral diamidophosphite ligand-assisted Pd-catalyzed Tsuji–Trost reaction between dimethyl malonate and prochiral 3-acetoxy-1,3-diphenylpropene in organic solvents using potassium carbonate as the base affords the substitution product in quantitative yields and with enantioselectivities up to 99% ee.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
A. A. Vasil'ev, S. E. Lyubimov, E. P. Serebryakov, V. A. Davankov, S. G. Zlotin, “Asymmetric Tsuji–Trost substitution in 3-acetoxy-1,3-diphenylpropene under phase-transfer conditions”, Mendeleev Commun., 22:1 (2012), 39–40
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc2731
https://www.mathnet.ru/rus/mendc/v22/i1/p39
Эта публикация цитируется в следующих 7 статьяx:
Erica Benedetti, Laurent Micouin, Comprehensive Heterocyclic Chemistry IV, 2022, 145
A. A. Vasil´ev, I. M. Aladzheva, O. V. Bykhovskaya, “Phase-transfer Tsuji—Trost allylation of CH-acids with the assistance of palladium complexes with bidentate PIII—N—PIII ligands”, Russ Chem Bull, 66:4 (2017), 661
K. N. Gavrilov, M. G. Maksimova, I. V. Chuchelkin, V. V. Lugovsky, S. V. Zheglov, V. K. Gavrilov, A. M. Perepukhov, “Chiral phosphite-type ligands based on ((4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) ((R,R)-TADDOL) with peripheral arylamino groups”, Russ Chem Bull, 66:7 (2017), 1265
T. A. Peganova, A. M. Kalsin, N. A. Ustynyuk, A. A. Vasil'ev, “Palladium(II) aminoiminophosphoranate complexes as cross-coupling catalysts”, Russ Chem Bull, 63:10 (2014), 2305
A. A. Vasil'ev, S. G. Zlotin, “Palladium-catalyzed allylation of malonic acid derivatives in heterogeneous systems containing ionic liquids”, Mendeleev Commun., 24:1 (2014), 23–25
A. A. Vasil'ev, I. V. Kuchurov, S. G. Zlotin, “Tsuji–Trost allylation of CH acids in supercritical carbon dioxide: advantages and problems”, Mendeleev Commun., 23:2 (2013), 84–85
Andrei A. Vasil'ev, Sergey E. Lyubimov, Edward P. Serebryakov, Vadim A. Davankov, Sergei G. Zlotin, “ChemInform Abstract: Asymmetric Tsuji—Trost Substitution in 3‐Acetoxy‐1,3‐diphenylpropene under Phase‐Transfer Conditions.”, ChemInform, 43:28 (2012)
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