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Эта публикация цитируется в 17 научных статьях (всего в 17 статьях)
New sterically-hindered catechols/o-benzoquinones. Reduction of 4,6-di-tert-butyl-2,3-dihydroxybenzaldehyde
M. V. Arsenyeva, E. V. Baranovb, M. P. Shuryginab, S. A. Chesnokovb, G. A. Abakumovb a N.I. Lobachevsky State University of Nizhni Novgorod, Nizhni Novgorod, Russian Federation
b G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
Аннотация:
Reduction of aldehyde group in 4,6-di-tert-butyl-2,3-dihydroxybenzaldehyde leads to methoxymethyl (NaBH4, MeOH) or methyl (Zn, MeOH) analogues, which were further oxidized into the corresponding o-benzoquinones. Their photostability in benzene increases substantially on replacement of the 6-positioned Me substituent with the CH2OMe group.
Ключевые слова:
catechol, o-quinone, X-Ray, quinomethide, reduction, photostability.
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc2278
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