Аннотация:
Hydrolysis of the C=C bond in 2-alkoxy-3-aryl(hetaryl)-propenals, depending upon substituents in the molecule, can proceed according to Markovnikov or Michael rule or with heterolytic opening of the cycle (in the case of 2-alkoxy-3-furylpropenal). Hydrolysis of 3-phenyl substituted alkoxypropenals bearing electron-withdrawing substituents (Cl, NO2) in the p-position has allowed a method for the preparation of corresponding benzylglyoxals (stable in enol form) to be developed.
Образец цитирования:
N. A. Keiko, N. V. Vchislo, E. A. Verochkina, Yu. A. Chuvashev, L. I. Larina, “Hydrolysis of (Z)-2-alkoxy-3-arylpropenals as a short-cut to benzylglyoxals”, Mendeleev Commun., 26:5 (2016), 431–433
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc2238
https://www.mathnet.ru/rus/mendc/v26/i5/p431
Эта публикация цитируется в следующих 4 статьяx:
Pernille Rose Jensen, Sebastian Meier, “Catalytic cycle of carbohydrate dehydration by Lewis acids: structures and rates from synergism of conventional and DNP NMR”, Chem. Commun., 56:46 (2020), 6245
Sergey N. Adamovich, “New atranes and similar ionic complexes. Synthesis, structure, properties”, Applied Organom Chemis, 33:7 (2019)
S. N. Adamovich, N. V. Vchislo, E. N. Oborina, I. A. Ushakov, I. B. Rozentsveig, “Novel α,β-unsaturated imine derivatives of 3-aminopropylsilatrane”, Mendeleev Commun., 27:5 (2017), 443–445
N. V. Vchislo, E. A. Verochkina, L. I. Larina, A. V. Vashchenko, Yu. A. Chuvashev, “Reaction of 2-alkoxy- and 2-hydroxypropenals with o-phenylenediamine: a route to benzimidazoles and quinoxalines”, Mendeleev Commun., 27:2 (2017), 166–168
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