Аннотация:
An isomer of C84 fullerene, D3d-C84(24)(CF3)12, has been isolated by the HPLC method from the products of trifluoromethylation of C84 fullerene mixture. Its molecular structure has been determined by a single crystal X-ray diffraction using synchrotron radiation. In the addition pattern, 12 CF3 groups are arranged as a loop of edge-sharing para-C6(CF3)2 hexagons. Isomer D6h-C84(24) has been identified in the form of a derivative for the first time.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
N. B. Tamm, S. I. Troyanov, “A minor isomer of C84 fullerene, D6h-C84(24), captured as a trifluoromethylated derivative, C84(CF3)12”, Mendeleev Commun., 26:4 (2016), 312–313
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc2197
https://www.mathnet.ru/rus/mendc/v26/i4/p312
Эта публикация цитируется в следующих 10 статьяx:
Nadezhda B. Tamm, Maria A. Fritz, Natalia A. Romanova, Alexey A. Goryunkov, Sergey I. Troyanov, “Synthesis, Structure, and Theoretical Study of Trifluoromethyl Derivatives of the IPR Isomer of C84 Fullerene, C84(11)(CF3)10,12,14”, ChemistrySelect, 7:19 (2022)
Yang-Rong Yao, Olivia Fernandez-Delgado, Luis Echegoyen, Handbook of Carbon-Based Nanomaterials, 2021, 19
Ayrat R. Khamatgalimov, Liana I. Yakupova, Valeri I. Kovalenko, “Features of molecular structure of small non-IPR fullerenes: the two isomers of C50”, Theor Chem Acc, 139:10 (2020)
Nadezhda B. Tamm, Maria A. Fritz, Sergey I. Troyanov, “Chloro‐ and Trifluoromethyl Derivatives of Fullerene C82, C82Cl14 and C82(CF3)14”, Asian J Org Chem, 9:6 (2020), 922
Nadezhda B. Tamm, Runnan Guan, Shangfeng Yang, Sergey I. Troyanov, “New Isolated‐Pentagon‐Rule Isomers of Fullerene C96 Captured as Chloro Derivatives”, Eur J Inorg Chem, 2020:21 (2020), 2092
N. B. Tamm, V. A. Brotsman, S. I. Troyanov, “Isolation and crystal structure of the trifluoromethyl derivative C84(24)(CF3)18 of a minor C84 fullerene isomer”, Mendeleev Commun., 30:4 (2020), 474–475
И. Е. Кареев, А. Е. Дутлов, В. П. Бубнов, “Роль карбида кремния в электродуговом синтезе высших фуллеренов”, ЖТФ, 90:1 (2020), 110–114; I. E. Kareev, A. E. Dutlov, V. P. Bubnov, “Role of silicon carbide in arc discharge synthesis of higher fullerenes”, Tech. Phys., 65:1 (2020), 102–106
Nadezhda B. Tamm, Daria V. Ignat'eva, Leonid A. Aslanov, Sergey I. Troyanov, “Synthesis, Isolation and Structures of Trifluoromethylated Fullerenes D2‐C76, C76(1)(CF3)10–18”, Chemistry — An Asian Journal, 13:16 (2018), 2027
Fei Jin, Song Wang, Nadezhda B. Tamm, Shangfeng Yang, Sergey I. Troyanov, “Synthesis, Isolation, and Trifluoromethylation of Two Isomers of C84‐Based Monometallic Cyanide Clusterfullerenes: Interplay between the Endohedral Cluster and the Exohedral Addends”, Angew Chem Int Ed, 56:39 (2017), 11990
Fei Jin, Song Wang, Nadezhda B. Tamm, Shangfeng Yang, Sergey I. Troyanov, “Synthesis, Isolation, and Trifluoromethylation of Two Isomers of C84‐Based Monometallic Cyanide Clusterfullerenes: Interplay between the Endohedral Cluster and the Exohedral Addends”, Angewandte Chemie, 129:39 (2017), 12152
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