Аннотация:
The enthalpies of dissolution of metastable rock salt (rs-ZnO) and thermodynamically stable wurtzite (w-ZnO) polymorphs of zinc oxide in aqueous H2SO4 have been measured in direct calorimetric experiments at 303K and 0.1MPa. Based on the obtained results, the standard enthalpy of the rs-ZnO to w-ZnO phase transition, ΔtrH = 11.7 ± 0.3kJ mol–1, has been determined.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
F. Yu. Sharikov, P. S. Sokolov, A. N. Baranov, V. L. Solozhenko, “On the thermodynamic aspect of zinc oxide polymorphism: calorimetric study of metastable rock salt ZnO”, Mendeleev Commun., 27:6 (2017), 613–614
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc2077
https://www.mathnet.ru/rus/mendc/v27/i6/p613
Эта публикация цитируется в следующих 6 статьяx:
Nicholas Farmer, Hugh St. C. O'Neill, “The miscibility gap between the rock salt and wurtzite phases in the MgO–ZnO binary system to 3.5 GPa”, Eur. J. Mineral., 35:6 (2023), 1051
Adrien Richard, Furio Corà, “Influence of Dispersion Interactions on the Polymorphic Stability of Crystalline Oxides”, J. Phys. Chem. C, 127:22 (2023), 10766
Petr S. Sokolov, Alexandre Courac, Vladimir L. Solozhenko, “Nanostructuring and stabilization of metastable rock-salt ZnO: impact of high-pressure media and compression geometry”, CrystEngComm, 25:40 (2023), 5740
Andrei N. Baranov, Petr S. Sokolov, Vladimir L. Solozhenko, “ZnO under Pressure: From Nanoparticles to Single Crystals”, Crystals, 12:5 (2022), 744
Konstantin V. Kamenev, Alexandre Courac, Petr S. Sokolov, Andrei N. Baranov, Felix Yu. Sharikov, Vladimir L. Solozhenko, “Heat Capacities of Nanostructured Wurtzite and Rock Salt ZnO: Challenges of ZnO Nano-Phase Diagram”, Solids, 2:1 (2021), 121
A. S. Stoporev, A. G. Kiiamov, M. A. Varfolomeev, T. V. Rodionova, A. Yu. Manakov, “Metastable ionic cubic structure I clathrate hydrate formed with tetra-n-butylammonium bromide”, Mendeleev Commun., 31:1 (2021), 17–19
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