Аннотация:
A single-step acid-catalyzed condensation of resorcinol or 2-methylresorcinol with 4-(prop-2-yn-1-yloxy)benzaldehyde stereoselectively gives exclusively rctt-isomers of new calix[4]- resorcinols in chair conformation bearing four terminal alkyne groups at aromatic substituents. Further alkylation of free hydroxy groups with propargyl bromide affords new calix[4]- resorcinols containing 12 terminal alkyne groups. Subsequent click reaction of these compounds with benzyl azide results in highly functionalized calix[4]resorcinols with 12 triazole- linked branches.
Образец цитирования:
I. R. Mironova (Knyazeva), D. K. Abdrafikova, K. M. Mukhamedyanova, V. V. Syakaev, B. M. Gabidullin, A. T. Gubaidullin, W. D. Habicher, A. R. Burilov, M. A. Pudovik, “Synthesis of novel highly functionalized triazole-linked calix[4]resorcinols via click reaction”, Mendeleev Commun., 27:6 (2017), 556–558
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc2057
https://www.mathnet.ru/rus/mendc/v27/i6/p556
Эта публикация цитируется в следующих 12 статьяx:
I. R. Mironova (Knyazeva), N. P. Romashov, V. V. Syakaev, D. P. Gerasimova, O. A. Lodochnikova, A. R. Burilov, “Synthesis and structural features of new calix[4]resorcinols with anthracene- and pyrene-ended isoxazole-containing fragments”, Mendeleev Commun., 34:3 (2024), 392–395
Manini Nayak, Kanyanjali Samal, Anita Pati, 2ND INTERNATIONAL CONFERENCE ON EMERGING SMART MATERIALS IN APPLIED CHEMISTRY (ESMAC-2021): ESMAC-2021, 2740, 2ND INTERNATIONAL CONFERENCE ON EMERGING SMART MATERIALS IN APPLIED CHEMISTRY (ESMAC-2021): ESMAC-2021, 2023, 060006
Héctor Manuel Pineda-Castañeda, Mauricio Maldonado-Villamil, Claudia Marcela Parra-Giraldo, Aura Lucía Leal-Castro, Ricardo Fierro-Medina, Zuly Jenny Rivera-Monroy, Javier Eduardo García-Castañeda, “Peptide-Resorcinarene Conjugates Obtained via Click Chemistry: Synthesis and Antimicrobial Activity”, Antibiotics, 12:4 (2023), 773
Héctor Manuel Pineda-Castañeda, Zuly Jenny Rivera-Monroy, Mauricio Maldonado, “Copper(I)-Catalyzed Alkyne–Azide Cycloaddition (CuAAC) “Click” Reaction: A Powerful Tool for Functionalizing Polyhydroxylated Platforms”, ACS Omega, 8:4 (2023), 3650
I. R. Mironova (Knyazeva), V. V. Syakaev, W. D. Habicher, A. R. Burilov, “New calix[4]resorcinol rccc diastereoisomer with terminal triple bonds: Synthesis, structural features and reactions”, Mendeleev Commun., 33:3 (2023), 397–400
I. R. Mironova (Knyazeva), N. P. Romashov, V. V. Syakaev, D. P. Gerasimova, O. A. Lodochnikova, A. R. Burilov, “Efficient synthesis of calix[4]resorcinol rccc diastereoisomers using high amount of trifluoroacetic acid in the chloroform medium”, Mendeleev Commun., 33:6 (2023), 844–846
Valentina V. Glushko, Olga S. Serkova, Vera I. Maslennikova, “Formation of octaalkylated rctt tetranaphthyl-resorcinarene derivatives containing biologically active components”, Tetrahedron Letters, 61:4 (2020), 151418
Olga S. Serkova, Valentina V. Glushko, Ilya Yu. Toropygin, Vera I. Maslennikova, “Synthesis of Triazole‐Containing rctt Tetra‐C‐Naphthyl‐Calix [4]resorcinarene and 1,1‐Dinaphthylmethane Derivatives”, ChemistrySelect, 5:39 (2020), 12168
I. R. Mironova (Knyazeva), T. P. Gerasimova, I. E. Kolesnikov, V. V. Syakaev, S. A. Katsyuba, A. R. Burilov, “Photophysical properties of new anthracene-ended calix[4]resorcinols”, Mendeleev Commun., 30:5 (2020), 650–653
I. R. Mironova (Knyazeva), V. I. Matveeva, V. V. Khrizanforova, V. V. Syakaev, Yu. H. Budnikova, W. D. Habicher, A. R. Burilov, “Click reaction in the synthesis of novel thiophosphorylated ligands for electrochemical hydrogen evolution”, Mendeleev Commun., 29:4 (2019), 388–390
Irina R. Knyazeva, Karina M. Mukhamedyanova, Victor V. Syakaev, Aidar T. Gubaidullin, Wolf D. Habicher, Alexander R. Burilov, “Synthesis of rccc- and rctt-diastereoisomers of novel triazole-containing calix[4]resorcinols”, Tetrahedron Letters, 59:17 (2018), 1683
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