Аннотация:
The reaction of the ruthenacarborane exo-nido-5,6,10-[Cl(Ph3P)2Ru]-5,6,10-(m-H)3-10-H-7,8-(Ph)2-7,8-C2B9H6 with phenylacetylene in dichloromethane in the presence of triethylamine at ambient temperature affords exo-nido-5,6,10-[(Ph3P)2Ru]-5,6-(μ-H)2-10-[μ-(PhC=CH)]-10-H-7,8-(Ph)2-7,8-C2B9H6 containing vinylene bridge group between carborane framework and ruthenium atom. Structure of the complex has been determined by X-ray diffraction study.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
A. Yu. Kostyukovich, D. I. D'yachikhin, I. D. Grishin, I. A. Godovikov, A. F. Smol'yakov, F. M. Dolgushin, D. F. Grishin, I. T. Chizhevsky, E. V. Balagurova, “Synthesis and molecular structure of exo-nido-ruthenacarborane containing vinylene bridge group”, Mendeleev Commun., 27:4 (2017), 392–393
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc2006
https://www.mathnet.ru/rus/mendc/v27/i4/p392
Эта публикация цитируется в следующих 2 статьяx:
A. A. Kaltenberg, A. M. Penkal', N. V. Somov, I. D. Grishin, “The synthesis of 3,3,3-(Ph2P)3CH-closo-3,1,2-RuC2B9H11, a novel ruthenacarborane complex with a chelate tridentate ligand”, Russ Chem Bull, 68:4 (2019), 770
John J. Jones, Laura E. English, Alasdair P.M. Robertson, Georgina M. Rosair, Alan J. Welch, “Mixed-ligand (triphenylphosphine)ruthenium complexes of diphenylcarborane by ligand manipulation and an asymmetric, bimolecular “symbiotic” cluster”, Journal of Organometallic Chemistry, 865 (2018), 65
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