Аннотация:
Zirconocene obtained from 6,6-dimethylfulvene ‘dimer’, being activated subsequently with triisobutylaluminium and methylalumoxane, catalyzes transformation of α-olefins into a mixture of vinylidene oligomers with minimal losses to isomerization, which allows one to consider this catalyst perspective for the synthesis of branched hydrocarbons with uniform structure.
Образец цитирования:
I. E. Nifant'ev, A. A. Vinogradov, A. A. Vinogradov, S. I. Bezzubov, P. V. Ivchenko, “Catalytic oligomerization of α-olefins in the presence of two-stage activated zirconocene catalyst based on 6,6-dimethylfulvene ‘dimer’”, Mendeleev Commun., 27:1 (2017), 35–37
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc1887
https://www.mathnet.ru/rus/mendc/v27/i1/p35
Эта публикация цитируется в следующих 19 статьяx:
Bingyu Shi, Man Liu, Jiangang Chen, “N-doped Metallocene Catalysts for Synthesis of High Quality Lubricant Base Oils from Fishcher–Tropsch Synthesized α-Olefin”, Catal Lett, 154:3 (2024), 1050
Lyudmila V. Parfenova, Pavel V. Kovyazin, Almira Kh. Bikmeeva, Eldar R. Palatov, Pavel V. Ivchenko, Ilya E. Nifant'ev, “Activation of metallocene hydride intermediates by methylaluminoxane in alkene dimerization and oligomerization”, Reac Kinet Mech Cat, 137:1 (2024), 269
Ilya E. Nifant'ev, Alexander A. Vinogradov, Alexey A. Vinogradov, Mikhail E. Minyaev, Vladimir V. Bagrov, Ildar I. Salakhov, Nadim M. Shaidullin, Anatoly E. Chalykh, Alexey V. Shapagin, Pavel V. Ivchenko, “Heterocene-catalyzed ethylene/oct-1-ene copolymerization under MAO-free and low-MAO conditions: The synthesis of highly statistical copolymers and their use in blending with HDPE”, Polymer, 272 (2023), 125836
Ilya E. Nifant'ev, Ildar I. Salakhov, Pavel V. Ivchenko, “Transition Metal–(μ-Cl)–Aluminum Bonding in α-Olefin and Diene Chemistry”, Molecules, 27:21 (2022), 7164
E. L. Iovleva, “Effect of the Dewaxol 7801 depressant-dispersant additive on summer diesel fuel”, Vestn. Voronež. gos. univ. inž. tehnol., 83:2 (2021), 180
Adis A. Tukhbatullin, Pavel V. Kovyazin, Glyus L. Sharipov, Lyudmila V. Parfenova, Pavel V. Ivchenko, Ilya E. Nifant'ev, “Photoluminescence and mechanoluminescence of solid‐state zirconocene dichlorides”, Luminescence, 36:4 (2021), 943
Ilya E. Nifant'ev, Pavel V. Ivchenko, Alexey A. Vinogradov, “Heterocycle-fused cyclopentadienyl metal complexes: Heterocene synthesis, structure and catalytic applications”, Coordination Chemistry Reviews, 426 (2021), 213515
I. E. Nifant'ev, A. A. Vinogradov, A. A. Vinogradov, P. V. Ivchenko, “Alternative mechanistic interpretation for unconventional catalytic behaviour of triisobutylaluminium-activated heterocenes in ethylene polymerization”, Mendeleev Commun., 31:4 (2021), 523–525
Ilya Nifant'ev, Alexander Vinogradov, Alexey Vinogradov, Stanislav Karchevsky, Pavel Ivchenko, “Experimental and Theoretical Study of Zirconocene-Catalyzed Oligomerization of 1-Octene”, Polymers, 12:7 (2020), 1590
Ilya Nifant'ev, Vladimir Bagrov, Alexander Vinogradov, Alexey Vinogradov, Sergey Ilyin, Nadezhda Sevostyanova, Sergey Batashev, Pavel Ivchenko, “Methylenealkane-Based Low-Viscosity Ester Oils: Synthesis and Outlook”, Lubricants, 8:5 (2020), 50
Ilya Nifant'ev, Pavel Ivchenko, “Fair Look at Coordination Oligomerization of Higher α-Olefins”, Polymers, 12:5 (2020), 1082
Ilya Nifant'ev, Alexander Vinogradov, Alexey Vinogradov, Pavel Ivchenko, “DFT Modeling of the Alternating Radical Copolymerization and Alder-Ene Reaction between Maleic Anhydride and Olefins”, Polymers, 12:4 (2020), 744
I. E. Nifant'ev, A. S. Lyadov, A. N. Tavtorkin, A. A. Vinogradov, A. A. Kochubeev, P. V. Ivchenko, “Branched alkylphosphinic acids demonstrate explicit anti-wear effect”, Mendeleev Commun., 29:5 (2019), 558–560
O. S. Soficheva, G. E. Bekmukhamedov, A. B. Dobrynin, J. W. Heinicke, O. G. Sinyashin, D. G. Yakhvarov, “α-Diphenylphosphino-N-(pyrazin-2-yl)glycine as a ligand in Ni-catalyzed ethylene oligomerization”, Mendeleev Commun., 29:5 (2019), 575–577
Ilya E. Nifant'ev, Alexander A. Vinogradov, Alexey A. Vinogradov, Igor V. Sedov, Viktor G. Dorokhov, Anton S. Lyadov, Pavel V. Ivchenko, “Structurally uniform 1-hexene, 1-octene, and 1-decene oligomers: Zirconocene/MAO-catalyzed preparation, characterization, and prospects of their use as low-viscosity low-temperature oil base stocks”, Applied Catalysis A: General, 549 (2018), 40
Norio Nakata, Kazuaki Nakamura, Akihiko Ishii, “Highly Efficient and 1,2-Regioselective Method for the Oligomerization of 1-Hexene Promoted by Zirconium Precatalysts with [OSSO]-Type Bis(phenolate) Ligands”, Organometallics, 37:15 (2018), 2640
I. E. Nifant'ev, A. A. Vinogradov, G. N. Bondarenko, S. A. Korchagina, A. V. Shlyakhtin, V. A. Roznyatovskii, P. V. Ivchenko, “Copolymers of Maleic Anhydride and Methylene Alkanes: Synthesis, Modification, and Pour Point Depressant Properties”, Polym. Sci. Ser. B, 60:4 (2018), 469
I. E. Nifant'ev, A. A. Vinogradov, A. A. Vinogradov, A. V. Churakov, P. V. Ivchenko, “Synthesis of zirconium(III) complex by reduction of O[SiMe2(η5-C5H4)]2ZrCl2 and its selectivity in catalytic dimerization of hex-1-ene”, Mendeleev Commun., 28:5 (2018), 467–469
Ilya Nifant'ev, Pavel Ivchenko, Alexander Tavtorkin, Alexey Vinogradov, Alexander Vinogradov, “Non-traditional Ziegler-Natta catalysis in α-olefin transformations: reaction mechanisms and product design”, Pure and Applied Chemistry, 89:8 (2017), 1017
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