Аннотация:
2-Alkylboriran-1-ols were obtained in a one-pot process by hydrolysis of 1-fluoro- and 1-chloroboriranes in 90–92% yield. The starting 1-haloboriranes were generated by cycloboration of α-olefins with BCl3·SMe2 or BF3·THF in the presence of Mg metal (acceptor of halogen ions) and Cp2TiCl2 catalyst.
Образец цитирования:
L. O. Khafizova, L. I. Khusainova, T. V. Tyumkina, K. S. Ryazanov, N. R. Porod'ko, U. M. Dzhemilev, “An original catalytic synthesis of boriran-1-ols”, Mendeleev Commun., 28:6 (2018), 577–578
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc1840
https://www.mathnet.ru/rus/mendc/v28/i6/p577
Эта публикация цитируется в следующих 6 статьяx:
L. I. Tulyabaeva, R. R. Salakhutdinov, T. V. Tyumkina, A. R. Tulyabaev, M. F. Abdullin, “One-pot synthesis of spiro[adamantane-2,2′-boriranes] via the Cp2TiCl2-catalyzed cycloboration of methyleneadamantane with boron halides”, Russ Chem Bull, 73:7 (2024), 1907
L. I. Tulyabaeva, R. R. Salakhutdinov, T. V. Tyumkina, A. R. Tulyabaev, “Cp2TiCl2-Catalyzed cycloboration of monoterpene methylene derivatives with BF3 · THF”, Russ Chem Bull, 72:10 (2023), 2446
Norberto Farfán, Pablo Labra-Vázquez, Rosa Santillan, Comprehensive Heterocyclic Chemistry IV, 2022, 534
Liliya I. Tulyabaeva, Rustam R. Salakhutdinov, Tatiyana V. Tyumkina, Arthur R. Tulyabaev, The 26th International Electronic Conference on Synthetic Organic Chemistry, 2022, 42
U. M. Dzhemilev, L. I. Khusainova, K. S. Ryazanov, L. O. Khafizova, “Boron-containing small rings: synthesis, properties, and application prospects”, Russ Chem Bull, 70:10 (2021), 1851
Liliya I. Khusainova, Leila O. Khafizova, Tatyana V. Tyumkina, Rustam R. Salakhutdinov, Usein M. Dzhemilev, “α,ω-Dienes in Cp2TiCl2-catalyzed synthesis of boriranes”, Journal of Organometallic Chemistry, 950 (2021), 121981
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