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Эта публикация цитируется в 2 научных статьях (всего в 2 статьях)
Synthesis, structure and magnetic properties of the dinuclear
complex [1,3-C6H4{NC(Ph)N(SiMe3)}2]3Dy2 coordinated
by ansa-bis(amidinate) ligands with a m-phenylene linker
G. G. Skvortsova, A. V. Cherkasova, J. Longb, J. Larionovab, A. A. Trifonovac
a G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
b Institut Charles Gerhardt Montpellier, UMR-5253 CNRS-UM-ENSCM, Ingenierie Moleculaire et Nano-Objets, Universite de Montpellier, Montpellier Cedex 5, France
c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Аннотация:
A salt metathesis reaction of anhydrous DyCl3 and [1,3-C6H4{NC(Ph)N(SiMe3)}2Li2(THF)2] in THF affords the complex [1,3-C6H4{NC(Ph)N(SiMe3)}2]3Dy2 regardless of a ratio between reagents. The assembling of a binuclear core results from a spanning coordination of the amidinate fragments of three m-bridging ansa-bis(amidinate) ligands to two Dy3+ ions. The magnetic properties of the product were studied by SQUID
magnetometry in a temperature range of 1.8–300 K.
Ключевые слова:
rare earth metals, ansa-bis(amidinate) ligand, synthesis, structure, magnetic properties.
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc1822
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