Аннотация:
Macrodiolides containing a 1Z,5Z-diene moiety were obtained with high selectivity (>98%) and in good yields (59–70%) by the Cu(OTf)2-catalyzed intermolecular esterification of aliphatic α,ω-dicarboxylic acids with tetradeca-5Z,9Z-diene- 1,14-diol. This diol was accessed by homocyclomagnesiation of hepta-5,6-dien-1-ol tetrahydropyranyl ether using EtMgBr/Mg reagent system and Cp2TiCl2 catalyst.
Образец цитирования:
V. A. D'yakonov, I. I. Islamov, E. M. Khusainova, U. M. Dzhemilev, “Original catalytic synthesis of macrodiolides containing a 1Z,5Z-diene moiety”, Mendeleev Commun., 28:5 (2018), 503–504
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc1815
https://www.mathnet.ru/rus/mendc/v28/i5/p503
Эта публикация цитируется в следующих 10 статьяx:
I. I. Islamov, I. V. Gaisin, U. M. Dzhemilev, V. A. D'yakonov, “Synthesis of macrocyclic mono- and diolides based on new ω-hydroxyalkadienoic acids with (Z,Z)-1,5-diene moiety”, Russ Chem Bull, 73:6 (2024), 1623
U. M. Dzhemilev, L. U. Dzhemileva, V. A. D'yakonov, “Metallacomplex catalysis in the synthesis of regular isoprenoids”, Russ Chem Bull, 72:2 (2023), 404
Vladimir A. D'yakonov, Lilya U. Dzhemileva, Usein M. Dzhemilev, “Natural compounds with bis-methylene-interrupted Z-double bonds: plant sources, strategies of total synthesis, biological activity, and perspectives”, Phytochem Rev, 20:1 (2021), 325
Vladimir A. D'yakonov, Ilgiz I. Islamov, Lilya U. Dzhemileva, Elina Kh. Makarova, Usein M. Dzhemilev, “Direct Synthesis of Polyaromatic Cyclophanes Containing Bis-Methylene-Interrupted Z-Double Bonds and Study of Their Antitumor Activity In Vitro”, IJMS, 22:16 (2021), 8787
Ilgiz Islamov, Adelya Yusupova, Lilya U. Dzhemileva, Usein Dzhemilev, The 25th International Electronic Conference on Synthetic Organic Chemistry, 2021, 6
Airat R. Tuktarov, Liliya L. Khuzina, Zarema R. Sadretdinova, Elina Kh. Makarova, Lilya U. Dzhemileva, Vladimir A. D'yakonov, Usein M. Dzhemilev, “Synthesis and cytotoxic activity of unsaturated macrolides and their hybrid molecules with a C60 fullerene”, Org. Biomol. Chem., 19:8 (2021), 1847
Ilgiz Islamov, Adelya Yusupova, Lilya U. Dzhemileva, Usein Dzhemilev, The 25th International Electronic Conference on Synthetic Organic Chemistry, 2021, 58
Lilya U. Dzhemileva, Vladimir A. D'yakonov, Ilgiz I. Islamov, Milyausha M. Yunusbaeva, Usein M. Dzhemilev, “New 1Z,5Z-diene macrodiolides: Catalytic synthesis, anticancer activity, induction of mitochondrial apoptosis, and effect on the cell cycle”, Bioorganic Chemistry, 99 (2020), 103832
S. A. Kondrashova, Yu. S. Ganushevich, S. V. Kharlamov, V. A. Milyukov, Sh. K. Latypov, “NMR study of the Ni complexes based on 1-alkyl-1,2-diphospholes”, Russ Chem Bull, 68:2 (2019), 374
V. A. D'yakonov, I. I. Islamov, L. U. Dzhemileva, M. M. Yunusbaeva, U. M. Dzhemilev, “Stereoselective synthesis and antitumor activity of macrodiolides containing 1Z,5Z-diene and 1,3-diyne moieties”, Mendeleev Commun., 29:6 (2019), 613–615
Обратная связь: