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Эта публикация цитируется в 4 научных статьях (всего в 4 статьях)
Methyl trifluoropyruvate – a new solvent for the production of fluorinated organic resorcinol–formaldehyde aerogels
S. A. Lermontova, A. N. Malkovaa, N. A. Sipyaginaa, A. V. Semakova, A. Y. Baranchikovb, V. K. Ivanovbc
a Institute of Physiologically Active Compounds, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
c National Research Tomsk Polytechnic University, Tomsk, Russian Federation
Аннотация:
Resorcinol–formaldehyde aerogels obtained in methyl trifluoropyruvate (MTFP) possess a fluorinated matrix due to the mechanism of electrophilic substitution in the resorcinol moiety with the formation of C–C bond. The use of MTFP as a solvent also substantially accelerates the formaldehyde–resorcinol interaction.
Ключевые слова:
resorcinol-formaldehyde aerogels, methyl trifluoropyruvate, fluorination, electrophilic substitution.
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc1679
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