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Эта публикация цитируется в 5 научных статьях (всего в 5 статьях)
Acid-base isomerization of hybrid molecules based on fullerene C60 and spiropyrans
A. R. Tuktarov, A. A. Khuzin, U. M. Dzhemilev
Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
Аннотация:
The reversible acid-base isomerization of fullerene C60 hybrid compounds with spiropyrans has been performed for the first time. It has been found that irradiation induces isomerization only for hybrid bearing NO2 group in the photochromic spiropyran part, while the treatment with trifluoroacetic acid induces isomerization for compounds containing NO2, Cl or F, i.e. irrespective of the nature of substituent in the spiropyran moiety.
Ключевые слова:
[60]fullerene, spiropyran, [2+3]-cycloaddition, pyrrolidinofullerene, reversible acid-base isomerization.
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https://www.mathnet.ru/rus/mendc1481
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