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Эта публикация цитируется в 5 научных статьях (всего в 5 статьях)
Undirected ortho-selectivity in C–H borylation of arenes catalyzed by NHC platinum(0) complexes
S. A. Rzhevskiya, M. A. Topchiya, Yu. D. Golenkoa, P. S. Gribanovb, G. K. Sterligovac, N. Yu. Kirilenkoac, A. A. Ageshinaa, M. V. Bermesheva, M. S. Nechaevac, A. F. Asachenkoab
a A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
c Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
Аннотация:
Borylation of arenes with bis(pinacolato)diboron catalyzed by sterically encumbered NHC platinum complexes proceeds predominantly at ortho-position even in the absence of a directing group (o:m:p ratio up to 10:3:1). The similar
borylation with pinacolborane would proceed less selectively.
Ключевые слова:
N-heterocyclic carbenes, platinum(0) complexes, borylation, arenes, organoboron compounds, regioselectivity, catalysis.
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc1254
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