P. V. Markov, N. S. Smirnova, G. N. Baeva, A. V. Bukhtiyarov, I. S. Mashkovsky, A. Yu. Stakheev, “Intermetallic PdxIny/Al2O3 catalysts with isolated single-atom Pd sites for one-pot hydrogenation of diphenylacetylene into trans-stilbene”, Mendeleev Commun., 30:4 (2020), 468

Аннотация: Novel one-pot synthesis of trans-stilbene comprises hydrogenation of diphenylacetylene into cis-stilbene followed by its hydroisomerization, over the catalyst being intermetallic Pd_xIn_y/Al₂O₃ system with isolated single-atom Pd₁ sites. The hydroisomerization rate in the process is comparable or exceeds the over-hydrogenation into 1,2-diphenylethane thus providing 76% yield of trans-stilbene in the case of Pd₂In₃/Al₂O₃ catalyst. This result presumably stems from the formation of ordered single-atom Pd₁ sites with favorable hydroisomerization ability on the surface of Pd_xIn_y catalysts.

Эта публикация цитируется в следующих 11 статьяx:

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Abdulaziz M. Alamer, Mengyao Ouyang, Faisal H. Alshafei, Muhammad Amtiaz Nadeem, Yahya Alsalik, Jeffrey T. Miller, Maria Flytzani-Stephanopoulos, E. Charles H. Sykes, Vasilios Manousiouthakis, Nathaniel M. Eagan, “Design of Dilute Palladium–Indium Alloy Catalysts for the Selective Hydrogenation of CO2 to Methanol”, ACS Catal., 13:15 (2023), 9987
Pavel V. Markov, Galina O. Bragina, Nadezhda S. Smirnova, Galina N. Baeva, Igor S. Mashkovsky, Evgeny Y. Gerasimov, Andrey V. Bukhtiyarov, Yan. V. Zubavichus, Alexander Y. Stakheev, “Single-Atom Alloy Pd1Ag10/CeO2–ZrO2 as a Promising Catalyst for Selective Alkyne Hydrogenation”, Inorganics, 11:4 (2023), 150
V. M. Akhmedov, N. E. Melnikova, Vs. M. Akhmedov, D. B. Tagiyev, “Tuning selectivity in the gas phase hydrogenation of phenylacetylene over the platinum—mesoporous carbon nitride composites using organic modifiers”, Russ Chem Bull, 71:2 (2022), 276
K. V. Vikanova, E. A. Redina, G. I. Kapustin, I. V. Mishin, N. A. Davshan, L. M. Kustov, “Selective hydrogenation of α,β-unsaturated aldehydes over Pt supported on cerium–zirconium mixed oxide of different composition”, Mendeleev Commun., 32:4 (2022), 488–491
Nadezhda S. Smirnova, Evgeny V. Khramov, Galina N. Baeva, Pavel V. Markov, Andrey V. Bukhtiyarov, Yan V. Zubavichus, Aleksander Y. Stakheev, “An Investigation into the Bulk and Surface Phase Transformations of Bimetallic Pd-In/Al2O3 Catalyst during Reductive and Oxidative Treatments In Situ”, Catalysts, 11:7 (2021), 859
Aliya N. Mukhamed'yarova, Svetlana R. Egorova, Oksana V. Nosova, Alexander A. Lamberov, “Influence of hydrothermal conditions on the phase transformations of amorphous alumina”, Mendeleev Communications, 31:3 (2021), 385
Nadezhda S. Smirnova, Igor S. Mashkovsky, Pavel V. Markov, Andrey V. Bukhtiyarov, Galina N. Baeva, Hanne Falsig, Alexander Y. Stakheev, “Local Structure of Pd1 Single Sites on the Surface of PdIn Intermetallic Nanoparticles: A Combined DFT and CO-DRIFTS Study”, Catalysts, 11:11 (2021), 1376