Аннотация:
Methyl 2-diazo-3-oxopropionates were obtained by in situ methoxycarbonylation of methyl ketones followed by diazo transfer onto active methylene group of the intermediate β-oxo esters. At the second stage, ‘sulfonyl-azide-free’ (SAFE) diazo transfer protocol in aqueous medium was employed.
Образец цитирования:
P. A. Zhmurov, D. V. Dar'in, O. Yu. Bakulina, M. Yu. Krasavin, “One-pot preparation of methyl 2-diazo-3-oxopropionates comprising an aqueous ‘sulfonyl-azide-free’ (SAFE) diazo transfer step”, Mendeleev Commun., 30:3 (2020), 311–312
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc1180
https://www.mathnet.ru/rus/mendc/v30/i3/p311
Эта публикация цитируется в следующих 4 статьяx:
Hiroki Tanimoto, Takenori Tomohiro, “Spot the difference in reactivity: a comprehensive review of site-selective multicomponent conjugation exploiting multi-azide compounds”, Chem. Commun., 60:84 (2024), 12062
D. S. Ramakrishna, “Preparation of Novel Chiral α-Diazocarbonyl Compounds Using Regitz's Methodology”, Organic Preparations and Procedures International, 54:2 (2022), 178
A. A. Komarova, D. V. Muratov, D. S. Perekalin, “Cyclopentadienyl rhodium(III) complexes as catalysts for the insertion of phenyldiazoacetate into E-H bonds”, Mendeleev Commun., 32:4 (2022), 482–484
E. G. Chupakhin, G. P. Kantin, D. V. Dar'in, M. Yu. Krasavin, “Convenient preparation of (E)-3-arylidene-4-diazopyrrolidine-2,5-diones in array format”, Mendeleev Commun., 31:1 (2021), 36–38
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