Аннотация:
New 10π-electron stabilized O,N-heterocyclic germylene was synthesized and structurally characterized for the first time. Its reduction with potassium in THF resulted in a unique low-valent germanium compound comprising the conjugated Ge4 chain, which was also characterized by the single crystal X-ray analysis. Bonding aspects in the latter compound have been additionally explored by DFT calculations, which revealed the occurrence of three σ bonds of different (covalent and dative) characters between the Ge atoms.
Образец цитирования:
K. V. Tsys, M. G. Chegerev, G. K. Fukin, A. G. Starikov, A. V. Piskunov, “Low-valent oligogermanium amidophenolate complex comprising a unique Ge4 chain”, Mendeleev Commun., 30:2 (2020), 205–208
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc1149
https://www.mathnet.ru/rus/mendc/v30/i2/p205
Эта публикация цитируется в следующих 21 статьяx:
Elena N. Nikolaevskaya, Mikhail A. Syroeshkin, Mikhail P. Egorov, Sergey S. Karlov, “Oxidative addition reactions of heavy analogs of carbenes (germylenes, stannylenes, plumbylenes) to σ-bonds”, Coordination Chemistry Reviews, 530 (2025), 216469
Tatiana N. Kocherova, Konstantin A. Martyanov, Roman V. Rumyantcev, Nikolay O. Druzhkov, Viacheslav A. Kuropatov, “Imination of Sterically Unshielded o‐Quinones in the Coordination Sphere of Zinc (II)”, ChemistrySelect, 9:22 (2024)
П. А. Петров, С. А. Николаевский, Д. С. Ямбулатов, А. А. Старикова, Т. С. Сухих, М. А. Кискин, М. Н. Соколов, И. Л. Еременко, “Разнолигандный анионный комплекс пивалата кобальта(II) с мостиковым триметилсилоксолигандом: синтез, строение и механизм формирования”, Žurnal neorganičeskoj himii, 68:9 (2023), 1255
K. V. Arsenyeva, A. V. Piskunov, “HETEROCYCLIC HEAVY ANALOGUES OF CARBENES: STRUCTURE AND CHEMICAL PROPERTIES. REVIEW”, J Struct Chem, 64:1 (2023), 1
A. V. Klimashevskaya, K. V. Arsenyeva, A. V. Cherkasov, I. A. Yakushev, A. V. Piskunov, “Synthesis, Structure, and Chemical Properties of 1,3,2-Benzoxazaphospholenes”, Russ J Gen Chem, 93:S3 (2023), S688
P. A. Petrov, S. A. Nikolaevskii, D. S. Yambulatov, T. S. Sukhikh, A. A. Starikova, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “Heteroleptic Cobalt Complexes with Abnormally Coordinated N-Heterocyclic Carbene”, Russ J Coord Chem, 49:7 (2023), 407
P. A. Petrov, S. A. Nikolaevskii, D. S. Yambulatov, T. S. Sukhikh, A. A. Starikova, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “Heteroleptic Cobalt Complexes with Abnormally Coordinated N-Heterocyclic Carbene”, Koordinacionnaâ himiâ, 49:7 (2023), 398
P. A. Petrov, S. A. Nikolaevskii, D. S. Yambulatov, A. A. Starikova, T. S. Sukhikh, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “Heteroleptic Anionic Cobalt(II) Pivalate Complex with a Bridging Trimethylsiloxy Ligand: Synthesis, Structure, and Formation Mechanism”, Russ. J. Inorg. Chem., 68:9 (2023), 1228
K. V. Arsenyeva, A. V. Klimashevskaya, M. A. Zherebtsov, M. G. Chegerev, A. V. Cherkasov, I. A. Yakushev, A. V. Piskunov, “Redox-Active Germylene Based on 2,4,6,8-Tetra-tert-butylphenoxazin-1-one: Synthesis, Structure, and Chemical Properties”, Russ J Coord Chem, 48:8 (2022), 464
Kseniya V. Arsenyeva, Anastasiya V. Klimashevskaya, Kira I. Pashanova, Olesya Yu. Trofimova, Maxim G. Chegerev, Alyona A. Starikova, Anton V. Cherkasov, Georgy K. Fukin, Ilya A. Yakushev, Alexandr V. Piskunov, “Stable heterocyclic stannylene: The metal, ligand‐centered reactivity, and effective catalytic hydroboration of aldehydes”, Applied Organom Chemis, 36:4 (2022)
A. V. Maleeva, I. V. Ershova, O. Yu. Trofimova, K. V. Arsenyeva, I. A. Yakushev, A. V. Piskunov, “Near-IR absorbing donor–acceptor charge-transfer gallium complex, an example from non-transition metal chemistry”, Mendeleev Commun., 32:1 (2022), 83–86
M. G. Chegerev, A. A. Starikova, A. G. Starikov, V. I. Minkin, “Computational search for redox isomerism in Ge and Sn bis-chelates with α-diimine ligands”, Mendeleev Commun., 32:1 (2022), 49–51
S. M. Ivanov, L. M. Mironovich, E. D. Daeva, “Synthesis and structure of 6-tert-butyl-5-triphenylgermyl-1,2,4-triazines”, Russ Chem Bull, 70:7 (2021), 1394
N. F. Lazareva, E. A. Zelbst, “New tridentate ligands based on 2-tert-butyl-4-methylphenol: synthesis and structure”, Russ Chem Bull, 70:7 (2021), 1349
Kseniya V. Arsenyeva, Maxim G. Chegerev, Anton V. Cherkasov, Kira I. Pashanova, Irina V. Ershova, Olesya Yu. Trofimova, Alexandr V. Piskunov, “Facile synthesis of digermylene oxide and its reactivity towards vanadocene: the first example of Cp2V–germylene coordination”, Mendeleev Communications, 31:3 (2021), 330
Kseniya V. Arsenyeva, Kira I. Pashanova, Olesya Yu. Trofimova, Irina V. Ershova, Maxim G. Chegerev, Alyona A. Starikova, Anton V. Cherkasov, Mikhail A. Syroeshkin, Anna Ya. Kozmenkova, Alexandr V. Piskunov, “O,N-Heterocyclic germylenes as efficient catalysts for hydroboration and cyanosilylation of benzaldehyde”, New J. Chem., 45:26 (2021), 11758
R. R. Aysin, S. S. Bukalov, “Probing the aromaticity of unsaturated N-heterocyclic carbenes and their heavy analogues with the EDDB criterion”, Russ Chem Bull, 70:4 (2021), 706
Gennady G. Kazakov, Nikolay O. Druzhkov, Evgeny V. Baranov, Alexandr V. Piskunov, Vladimir K. Cherkasov, “The reactivity of N-heterocyclic germylenes and stannylenes based on 9,10-phenanthrendiimines towards metal carbonyls and sulfur”, Journal of Organometallic Chemistry, 946-947 (2021), 121887
R. R. Aysin, A. V. Lalov, S. S. Bukalov, “Probing the aromaticity in 2,3-pyrido-annulated N-heterocyclic carbene and its heavier analogues”, Mendeleev Commun., 31:6 (2021), 797–799
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