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Письма в Журнал экспериментальной и теоретической физики, 2010, том 91, выпуск 8, страницы 457–460
(Mi jetpl702)
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Эта публикация цитируется в 11 научных статьях (всего в 11 статьях)
КОНДЕНСИРОВАННЫЕ СРЕДЫ
Phase segregation in Na$_x$CoO$_2$ for large Na contents
T. A. Platovaab, I. R. Mukhamedshinab, A. V. Dooglavb, H. Alloula a Laboratoire de Physique des Solides, UMR 8502, UniversitéParis-Sud, 91405 Orsay, France
b Physics Department, Kazan State University
Аннотация:
We have investigated a set of sodium cobaltates (Na$_x$CoO$_2$) samples with various sodium content $(0.67\leq x\leq0.75)$ using Nuclear Quadrupole Resonance (NQR). The four different stable phases and an intermediate one have been recognized. The NQR spectra of $^{59}$Co allowed us to clearly differentiate the pure phase samples which could be easily distinguished from multi-phase samples. Moreover, we have found that keeping samples at room temperature in contact with humid air leads to destruction of the phase purity and loss of sodium content. The high sodium content sample evolves progressively into a mixture of the detected stable phases until it reaches the $x=2/3$ composition which appears to be the most stable phase in this part of phase diagram.
Поступила в редакцию: 12.03.2010
Образец цитирования:
T. A. Platova, I. R. Mukhamedshin, A. V. Dooglav, H. Alloul, “Phase segregation in Na$_x$CoO$_2$ for large Na contents”, Письма в ЖЭТФ, 91:8 (2010), 457–460; JETP Letters, 91:8 (2010), 421–424
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/jetpl702 https://www.mathnet.ru/rus/jetpl/v91/i8/p457
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Страница аннотации: | 183 | PDF полного текста: | 57 | Список литературы: | 25 |
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