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Письма в Журнал экспериментальной и теоретической физики, 2012, том 95, выпуск 3, страницы 179–184
(Mi jetpl2438)
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Эта публикация цитируется в 30 научных статьях (всего в 30 статьях)
КОНДЕНСИРОВАННОЕ СОСТОЯНИЕ
Universal crossover of liquid dynamics in supercritical region
V. V. Brazhkina, Yu. D. Fomina, A. G. Lyapina, V. N. Ryzhova, K. Trachenkob a Institute for High Pressure Physics, Russian Academy of Sciences
b School of Physics, Queen Mary, University of London
Аннотация:
We demonstrate that all liquids in supercritical region may exist in two qualitatively different states: solid-like and gas-like. Solid-like to gas-like crossover corresponds to the condition $\tau\approx\tau_0$, where $\tau$ is liquid relaxation time and $\tau_0$ is the minimal period of transverse waves. This condition corresponds to the loss of shear stiffness of a liquid at all frequencies and defines a new narrow crossover zone on the phase diagram. We show that the intersection of this zone corresponds to the disappearance of high-frequency sound, qualitative changes of diffusion and viscous flow, increase of particle thermal speed to half of the speed of sound and reduction of the constant volume specific heat to $2k_{\rm B}$ per particle. The new crossover is universal: it separates two liquid states at arbitrarily high pressure and temperature, and even exists in systems where liquid – gas transition and the critical point are absent overall.
Поступила в редакцию: 11.01.2012
Образец цитирования:
V. V. Brazhkin, Yu. D. Fomin, A. G. Lyapin, V. N. Ryzhov, K. Trachenko, “Universal crossover of liquid dynamics in supercritical region”, Письма в ЖЭТФ, 95:3 (2012), 179–184; JETP Letters, 95:3 (2012), 164–169
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/jetpl2438 https://www.mathnet.ru/rus/jetpl/v95/i3/p179
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