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Физика твердого тела, 2021, том 63, выпуск 3, страница 344
(Mi ftt10152)
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Эта публикация цитируется в 1 научной статье (всего в 1 статье)
Металлы
Thermoelectric properties of metallic hexaborides $R$B$_6$ ($R$ = La, Pr, Nd, Gd)
M. Anisimova, N. Samarina, S. Demisheva, A. Bogacha, V. Voronova, N. Shitsevalovab, A. Levchenkob, V. Philippovb, V. Glushkova a Prokhorov General Physics Institute of the Russian Academy of Sciences, 119991 Moscow, Russia
b Frantsevich Institute for Problems of Materials Science, National Academy of Sciences of Ukraine, 03680 Kyiv, Ukraine
Аннотация:
Seebeck coefficient has been studied on the single crystals of metallic hexaborides $R$B$_6$ ($R$ = La, Pr, Nd, Gd) at temperatures of 2–300 K. The experiment has shown that the signal is limited by the values $|S|\le$ 1.5 $\mu$V/K for all tested materials. The data obtained for the systems LaB$_6$ and GdB$_6$ were approximated by phonon drag contribution caused by quasi-local (Einstein) mode with characteristic temperatures $\Theta_E$(LaB$_6$) $\approx$ 240 K and $\Theta_E$(GdB$_6$) $\approx$ 180 K. On the contrary, the crystal-line electric field effect induces the inversion between negative and positive types of thermoelectricity, which complicates the simulation of phonon drag in the case of PrB$_6$ and NdB$_6$.
Ключевые слова:
Seebeck effect, phonon drag, hexaborides, metals.
Образец цитирования:
M. Anisimov, N. Samarin, S. Demishev, A. Bogach, V. Voronov, N. Shitsevalova, A. Levchenko, V. Philippov, V. Glushkov, “Thermoelectric properties of metallic hexaborides $R$B$_6$ ($R$ = La, Pr, Nd, Gd)”, Физика твердого тела, 63:3 (2021), 344; Phys. Solid State, 63:3 (2021), 414–419
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/ftt10152 https://www.mathnet.ru/rus/ftt/v63/i3/p344
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