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This article is cited in 2 scientific papers (total in 2 papers)
Method for experimental data processing concerning chemical reaction rates in low-atomic gases
A. A. Belovab, N. N. Kalitkinc a Faculty of Physics, Lomonosov Moscow State University, Moscow, 119991 Russia
b RUDN University, Moscow, 117198 Russia
c Federal Research Center Keldysh Institute of Applied Mathematics, Russian Academy of Sciences, Moscow, 125047 Russia
Abstract:
A new method for joint processing of experimental data from various laboratories based on their approximation by the generalized Arrhenius law is proposed. The method is based on the construction of a system of functions that are orthogonal on a given set of points with arbitrary weights. As a result, the confidence intervals of the approximation coefficients can be estimated and the number of terms required for the approximation can be correctly determined. The performance of the method is demonstrated as applied to reactions of hydrogen combustion in air that are important at $T<1000$ K. High accuracy of reaction rate approximation is achieved.
Key words:
chemical reactions, hydrogen combustion, rate constants, experimental data processing, orthogonal polynomials.
Received: 05.10.2019 Revised: 05.10.2019 Accepted: 10.03.2020
Citation:
A. A. Belov, N. N. Kalitkin, “Method for experimental data processing concerning chemical reaction rates in low-atomic gases”, Zh. Vychisl. Mat. Mat. Fiz., 60:7 (2020), 1239–1247; Comput. Math. Math. Phys., 60:7 (2020), 1199–1207
Linking options:
https://www.mathnet.ru/eng/zvmmf11107 https://www.mathnet.ru/eng/zvmmf/v60/i7/p1239
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Abstract page: | 112 | References: | 22 |
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