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Uchenye Zapiski Kazanskogo Universiteta. Seriya Fiziko-Matematicheskie Nauki, 2012, Volume 154, Book 3, Pages 26–33 (Mi uzku1135)  

This article is cited in 1 scientific paper (total in 1 paper)

Spin Properties of a New Iron Complex with Schiff Base

A. V. Pyataeva, R. A. Manapova, N. E. Domrachevab, M. S. Gruzdevc, U. V. Chervonovac, A. G. Ivanovad

a Kazan (Volga Region) Federal University
b Zavoisky Physical Technical Institute, Kazan Scientific Center of the Russian Academy of Sciences
c G. A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, Ivanovo
d Institute of Physics, Kazan (Volga region) Federal University
Full-text PDF (412 kB) Citations (1)
References:
Abstract: An iron(III) complex with bis-3,4,5-tri(tetradecyloxy)benzoyloxy-4-salicylidene-${\rm{N'}}$-ethyl-N-ethylenediamine with outer-sphere anion NO$^{-}_{3}$ has been investigated by M\"оssbauer spectroscopy, differential scanning calorimetry (DSC), and polarized light microscopy. It has been found that at a temperature of 300 K the iron(III) ions are in a high-spin (S = 5/2) state and are likely to form a dimeric structure. During the heating and cooling cycles, the complex undergoes a glass–solid phase transition at 41.14 $^{\circ}{\rm{C}}$, a solid–solid transition at 49.52 $^{\circ}{\rm{C}}$, and a solid–liquid transition at 144 $^{\circ}{\rm{C}}$. A decrease in temperature leads to a spin-crossover transition, and at 80 K the spectrum area of the low-spin component is about $\approx$ 3.5%. A further decrease in temperature leads to magnetic spin correlations and antiferromagnetic ordering in the system of high-spin Fe(III) centers.
Keywords: iron complexes, spin state, hyperfine interaction, Mössbauer spectroscopy, differential scanning calorimetry, polarized light microscopy.
Received: 15.08.2012
Document Type: Article
UDC: 539.21:543.429.3
Language: Russian
Citation: A. V. Pyataev, R. A. Manapov, N. E. Domracheva, M. S. Gruzdev, U. V. Chervonova, A. G. Ivanova, “Spin Properties of a New Iron Complex with Schiff Base”, Uchenye Zapiski Kazanskogo Universiteta. Seriya Fiziko-Matematicheskie Nauki, 154, no. 3, Kazan University, Kazan, 2012, 26–33
Citation in format AMSBIB
\Bibitem{PyaManDom12}
\by A.~V.~Pyataev, R.~A.~Manapov, N.~E.~Domracheva, M.~S.~Gruzdev, U.~V.~Chervonova, A.~G.~Ivanova
\paper Spin Properties of a New Iron Complex with Schiff Base
\serial Uchenye Zapiski Kazanskogo Universiteta. Seriya Fiziko-Matematicheskie Nauki
\yr 2012
\vol 154
\issue 3
\pages 26--33
\publ Kazan University
\publaddr Kazan
\mathnet{http://mi.mathnet.ru/uzku1135}
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  • https://www.mathnet.ru/eng/uzku/v154/i3/p26
  • This publication is cited in the following 1 articles:
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