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This article is cited in 11 scientific papers (total in 11 papers)
METHODOLOGICAL NOTES
On the physical meaning of the molecular point group
A. V. Burenin Institute of Applied Physics, Russian Academy of Sciences
Abstract:
It is argued that the most important result of applying the Born–Oppenheimer approximation to intramolecular dynamics is not the separation of electron and nuclear motions but the transition to the problem formulation in which the symmetry properties of the point group transformations characterizing a molecule in a chosen electron state can be correctly taken into account. It is shown that this group should be used as a rigorous symmetry group of total (electron–vibration–rotational) motion in this state.
Received: November 9, 2005
Citation:
A. V. Burenin, “On the physical meaning of the molecular point group”, UFN, 176:8 (2006), 847–856; Phys. Usp., 49:8 (2006), 821–829
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https://www.mathnet.ru/eng/ufn354 https://www.mathnet.ru/eng/ufn/v176/i8/p847
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Abstract page: | 353 | Full-text PDF : | 96 | References: | 71 | First page: | 1 |
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