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Uspekhi Fizicheskikh Nauk, 2003, Volume 173, Number 1, Pages 51–68
DOI: https://doi.org/10.3367/UFNr.0173.200301c.0051 (Mi ufn2098) 		 
This article is cited in 40 scientific papers (total in 40 papers)

REVIEWS OF TOPICAL PROBLEMS

Ionic conductivity and complexation in liquid dielectrics

A. I. Zhakin

Kursk State Technical University
Full-text PDF (2964 kB) Citations (40)
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DOI: https://doi.org/10.3367/UFNr.0173.200301c.0051
Abstract: Electronic and ionic conductivity in nonpolar liquids is reviewed. Theoretical results on ionic complexation (formation of ion pairs and triplets, dipole–dipole chains, ion–dipole clusters) in liquid dielectrics in an intense external electric field are considered, and the relation between the complexation process and ionic conductivity is discussed. Experimental results supporting the possibility of complexation are presented and compared with theoretical calculations. Onsager's theory about the effect of an intense external electric field on ion-pair dissociation is corrected for the finite size of ions.
Received: November 12, 2001
Revised: May 30, 2002
English version:
Physics–Uspekhi, 2003, Volume 46, Issue 1, Pages 45–61
DOI: https://doi.org/10.1070/PU2003v046n01ABEH001141
Bibliographic databases:
Document Type: Article
PACS: 51.50.+v, 66.10.Ed, 82.30.Fi
Language: Russian
Citation: A. I. Zhakin, “Ionic conductivity and complexation in liquid dielectrics”, UFN, 173:1 (2003), 51–68; Phys. Usp., 46:1 (2003), 45–61
Citation in format AMSBIB
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    • This publication is cited in the following 40 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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