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Uspekhi Fizicheskikh Nauk, 1996, Volume 166, Number 1, Pages 33–62
DOI: https://doi.org/10.3367/UFNr.0166.199601b.0033
(Mi ufn1145)
 

This article is cited in 75 scientific papers (total in 75 papers)

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Atomic and vacancy ordering in nonstoichiometric carbides

A. A. Rempel

Institute of Solid State Chemistry, Urals Branch of the Russian Academy of Sciences, Ekaterinburg
Abstract: An analysis of the electronic structure of highly nonctoichiometric transition-metal carbides in both ordered and disordered states is given, which explains the influence of atomic and vacancy order on the physical properties of the carbides. It is shown that the dependence of carbide properties on the arrangement of carbon atoms in the nonmetal sublattice is related to both the symmetry space group of the crystal and the symmetry of the nearest-neighbour environment of the carbide atoms. By analysing order—disorder phase transition data, experimental information on atomic and vacancy order in carbides is obtained in order to explain the nature of superstructures at high vacancy concentrations.
Received: December 1, 1995
English version:
Physics–Uspekhi, 1996, Volume 39, Issue 1, Pages 31–56
DOI: https://doi.org/10.1070/PU1996v039n01ABEH000126
Bibliographic databases:
Document Type: Article
PACS: 61.50.K, 61.70.B, 64.80, 70.00
Language: Russian


Citation: A. A. Rempel, “Atomic and vacancy ordering in nonstoichiometric carbides”, UFN, 166:1 (1996), 33–62; Phys. Usp., 39:1 (1996), 31–56
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  • This publication is cited in the following 75 articles:
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